- Ethyl (4-methylthiophenyl)acetate
- ETHYL (4-NITROBENZOYL)ACETATE
- Ethyl (E)-7-[4-(4'-fluorophenyl)-2-(cyclopropyl)-3-quinolinyl]-5-hydroxy-3-oxo-6-heptenoate
- Ethyl (pentafluorobenzoyl)acetate
- Ethyl (R)-(+)-4-chloro-3-hydroxybutyrate
- Ethyl (R)-1-Boc-nipecotate
- Ethyl (R)-2-hydroxy-4-phenylbutyrate
- Ethyl (R)-3-hydroxy-3-phenylpropionate
- Ethyl (R)-3-hydroxybutyrate
- Ethyl [1,2,4]triazolo[1,5-a]pyridine-2-carboxylate
- 36242-50-9Benzoic acid, 4-(methylamino)-3-nitro-, methyl ester
- 3624-46-2Thymidine5'-(tetrahydrogen triphosphate), tetrasodium salt (8CI,9CI)
- 36244-70-9Benzonitrile,4-[(1S)-1-aminoethyl]-
- 36245-95-1Benzonitrile,2,3,4,5-tetrachloro-
- 3624-68-81-Naphthalenesulfonicacid, 6-[2-(5-chloro-2-hydroxy-3-sulfophenyl)diazenyl]-5-hydroxy-, sodium salt(1:2)
- 362483-23-62(5H)-Furanone, 3-(3-chlorophenyl)-5-(hydroxymethyl)-
- 362487-78-3(3R,4R)-rel-Tetrahydro-N-hydroxy-4-[[4-[(2-methyl-4-quinolinyl)methoxy]benzoyl]amino]-2H-pyran-3-carboxamide
- 362489-56-3TRANS-4-AMINO-1-N-BOC-3-PYRROLIDINECARBOXYLIC ACID ETHYL ESTER
- 362492-00-01,2(1H)-Isoquinolinedicarboxylicacid, 3,4-dihydro-6-hydroxy-, 2-(1,1-dimethylethyl) ester
- 362505-84-8Relacatib
Hot Products
- 104987-11-3Tacrolimus
- 141-53-7Sodium formate
- 8001-54-5Quaternary ammonium compounds, alkylbenzyldimethyl, chlorides
- 9003-39-8Povidone
- 10161-34-9Trenbolone acetate
- 402957-28-2Telaprevir
- 68-19-9Cyanocobalamin
- 7631-86-9Silicon dioxide
- 302-79-4Tretinoin
- 77-92-9Citric acid
|
Basic Information |
|
Post buying leads |
|
Suppliers |
|
Cas Database |
| Name |
Ethyl malonyl chloride |
EINECS | 252-934-5 |
| CAS No. | 36239-09-5 | Density | 1.223 g/cm3 |
| PSA | 34.14000 | LogP | 1.54340 |
| Solubility | Reacts with water | Melting Point |
N/A |
| Formula | C5H7ClO3 | Boiling Point | 172.4 °C at 760 mmHg |
| Molecular Weight | 150.562 | Flash Point | 65 °C |
| Transport Information | UN 3265 8/PG 3 | Appearance | clear yellow to brown liquid |
| Safety | 7-26-36/37/39-45-36/39 | Risk Codes | 14-34 |
| Molecular Structure |
|
Hazard Symbols |
 C
|
| Synonyms |
Aceticacid, (chloroformyl)-, ethyl ester (6CI,7CI);(Chlorocarbonyl)acetic acid ethylester;(Chloroformyl)acetic acid ethyl ester;(Ethoxycarbonyl)acetyl chloride;2-(Ethoxycarbonyl)acetyl chloride;3-Chloro-3-oxopropanoic acid ethyl ester;Carbethoxyacetyl chloride;Carbethoxyethanoyl chloride;Carboethoxyacetylchloride;Ethoxymalonyl chloride;Ethyl (chlorocarbonyl)acetate;Ethyl(chloroformyl)acetate;Ethyl 3-chloro-3-oxopropanoate;Ethyl3-chloro-3-oxopropionate;Ethyl 3-oxo-3-chloropropanoate; |
Article Data | 34 |
Ethyl malonyl chloride Synthetic route
- 1071-46-1
hydrogen ethyl malonate
- 36239-09-5
ethyl chlorocarbonylacetate
| Conditions | Yield |
|---|---|
| With thionyl chloride | 91% |
| With thionyl chloride; N,N-dimethyl-formamide In chloroform Heating; | 70% |
| With oxalyl dichloride In dichloromethane for 3h; Reflux; | 69% |
- 6148-64-7
ethyl potassium malonate
- 36239-09-5
ethyl chlorocarbonylacetate
| Conditions | Yield |
|---|---|
| With oxalyl dichloride In benzene for 1h; Ambient temperature; | 90% |
| With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane at 0 - 20℃; for 2h; Inert atmosphere; | 41% |
| With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane at 0 - 20℃; for 2h; Inert atmosphere; |
- 105-53-3
diethyl malonate
- 36239-09-5
ethyl chlorocarbonylacetate
| Conditions | Yield |
|---|---|
| (i) (hydrolysis), (ii) SOCl2, PhNMe2; Multistep reaction; | |
| Multi-step reaction with 2 steps 1: KOH / ethanol / 1 h / 0 - 20 °C 2: 90 percent / oxaloyl chloride / benzene / 1 h / Ambient temperature View Scheme | |
| Multi-step reaction with 3 steps 1: water; sodium hydroxide / ethanol / 1 h / Reflux 2: hydrogenchloride; water / pH 3 3: thionyl chloride / 72 h / 20 °C View Scheme |
- 88-95-9
Phthaloyl dichloride
- 36239-09-5
ethyl chlorocarbonylacetate
| Conditions | Yield |
|---|---|
| at 100 - 110℃; und Fraktionieren unter 20-25 mm; |
- 36239-09-5
ethyl chlorocarbonylacetate
| Conditions | Yield |
|---|---|
| With thionyl chloride at 0℃; |
- 36239-09-5
ethyl chlorocarbonylacetate
| Conditions | Yield |
|---|---|
| With thionyl chloride; diethyl ether |
- 105-53-3
diethyl malonate
- 36239-09-5
ethyl chlorocarbonylacetate
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: 79 percent / aq. KOH 2: 91 percent / SOCl2 View Scheme |
- 105-53-3
diethyl malonate
- 36239-09-5
ethyl chlorocarbonylacetate
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: KOH / ethanol 2: SOCl2 View Scheme |
- 4503-58-6
benzyl 2-(2-ethoxy-2-ethoxyethyl)-1-hydrazinecarboxylate
- 36239-09-5
ethyl chlorocarbonylacetate
- 98381-05-6
benzyl 2-ethoxycarbonylacetyl-2-(ethoxycarbonylmethyl)hydrazine-1-carboxylate
| Conditions | Yield |
|---|---|
| With triethylamine In benzene 1.) 0 deg C, 1 h, 2.) RT, 19 h; | 100% |
| With triethylamine In benzene Yield given; |
Ethyl malonyl chloride Chemical Properties
Molecular structure of Ethyl malonyl chloride (CAS NO.36239-09-5) is:
Product Name: Ethyl malonyl chloride
CAS Registry Number: 36239-09-5
IUPAC Name: ethyl 3-chloro-3-oxopropanoate
Molecular Weight: 150.56028 [g/mol]
Molecular Formula: C5H7ClO3
XLogP3: 1.3
H-Bond Donor: 0
H-Bond Acceptor: 3
EINECS: 252-934-5
Surface Tension: 35 dyne/cm
Density: 1.223 g/cm3
Flash Point: 65 °C
Enthalpy of Vaporization: 40.87 kJ/mol
Boiling Point: 172.4 °C at 760 mmHg
Vapour Pressure: 1.34 mmHg at 25°C
Refractive index: n20/D 1.429(lit.)
Storage temp.: 2-8 °C
Water Solubility: Reacts
Sensitive: Moisture Sensitive
Product Categories: Aliphatics
Ethyl malonyl chloride Safety Profile
Safty information about Ethyl malonyl chloride (CAS NO.36239-09-5) is:
Hazard Codes: 
C
Risk Statements: 14-34
R14 :Reacts violently with water.
R34:Causes burns.
Safety Statements: 7-26-36/37/39-45-36/39
S7:Keep container tightly closed.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/39:Wear suitable protective clothing and eye / face protection.
RIDADR: UN 3265 8/PG 3
WGK Germany: 3
F: 10-21
Hazard Note: Corrosive
HazardClass: 8
PackingGroup: II
Ethyl malonyl chloride Specification
Ethyl malonyl chloride , its cas register number is 36239-09-5. It also can be called Propanoic acid, 3-chloro-3-oxo-, ethyl ester ; Ethyl (chloroformyl)acetate ; Ethyl 3-chloro-3-oxopropionate .It is a clear yellow to brown liquid.
What can I do for you?
Get Best Price
