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Cas Database |
| Name |
Ethyl methyl carbonate |
EINECS | 208-760-7 | |
| CAS No. | 623-53-0 | Density | 0.997 g/cm3 | |
| PSA | 35.53000 | LogP | 0.78930 | |
| Solubility | insoluble in water | Melting Point |
-14.5 °C |
|
| Formula | C4H8O3 | Boiling Point | 107.5 °C at 760 mmHg | |
| Molecular Weight | 104.106 | Flash Point | 26.7 °C | |
| Transport Information | N/A | Appearance | colorless liquid | |
| Safety | 16 | Risk Codes | 10 | |
| Molecular Structure |
|
Hazard Symbols | Xi | |
| Synonyms |
Methyl ethyl carbonate; |
Article Data | 67 | |
Ethyl methyl carbonate Synthetic route
| Conditions | Yield |
|---|---|
| With 1,2-dimethyl-1H-imidazole at 0 - 20℃; for 1h; Product distribution / selectivity; | 98.1% |
| With 1-methyl-1H-imidazole at 0 - 20℃; for 1h; | 97.4% |
| With 1-methyl-1H-imidazole In bis-2-propyl carbonate at 0 - 20℃; for 1h; | 97.6% |
| Conditions | Yield |
|---|---|
| With dicobalt octacarbonyl at 180℃; for 1h; chemoselective reaction; | 98% |
| With Novozyme 435 at 60℃; for 24h; Green chemistry; Enzymatic reaction; | 90.3% |
| With lanthanum(III) chloride; calcium chloride; sodium hydroxide at 90℃; for 12h; Reagent/catalyst; Molecular sieve; Glovebox; | 51.47% |
- 132819-56-8
3-Methyl-4-phenyl-4H-pyridine-1-carboxylic acid ethyl ester
A
- 2052-92-8
3-methyl-4-phenyl-pyridine
B
- 623-53-0
ethyl methyl carbonate
| Conditions | Yield |
|---|---|
| With sodium methylate In methanol at 18℃; anodic oxidation (graphite-rod electrodes), 6 F/mol passed through the solution; | A 90% B n/a |
| Conditions | Yield |
|---|---|
| With Zeolitic imidazole framework (ZIF)-67 at 100℃; for 24h; Reagent/catalyst; Concentration; | 83.39% |
| With Mg/Fe oxide calcined at 400°C at 100℃; for 1.5h; Catalytic behavior; Reagent/catalyst; Temperature; | 66% |
| With Zn(2-methylimidazolate)2 at 100℃; for 3h; Reagent/catalyst; Temperature; Time; | 65.7% |
- 64-17-5
ethanol
- 616-38-6
carbonic acid dimethyl ester
A
- 623-53-0
ethyl methyl carbonate
B
- 105-58-8
Diethyl carbonate
| Conditions | Yield |
|---|---|
| With sodium methylate In methanol at 69 - 120℃; for 6h; Reflux; | A n/a B 73% |
| With silica-alumina at 78℃; under 760.051 Torr; for 2h; pH=11; Reagent/catalyst; Temperature; | A 63.9% B n/a |
| With 15percentMgO-5percentMgCl-2percentLa2CO3 supported on Al2O3-SiO2 at 200℃; under 760.051 Torr; Reagent/catalyst; Temperature; | A 57.37% B n/a |
- 64-17-5
ethanol
- 584-07-6
methyl N-hydroxycarbamate
A
- 623-53-0
ethyl methyl carbonate
B
- 616-38-6
carbonic acid dimethyl ester
| Conditions | Yield |
|---|---|
| With lead dioxide In dichloromethane at 40℃; for 0.166667h; | A 14.3% B 70% |
| With lead dioxide at 40℃; for 0.166667h; Product distribution; reaction at -10 deg C; other alcohols, water; oxidation of alkyl N-hydroxycarbamates in the presence of alcohols; competitive alcoholysis; effect of the nature of alkyl group, alcohol reactivity, temperature on the product ratio; | A 14.3% B 70% |
- 67-56-1
methanol
- 589-41-3
ethyl N-hydroxylcarbamate
A
- 623-53-0
ethyl methyl carbonate
B
- 105-58-8
Diethyl carbonate
| Conditions | Yield |
|---|---|
| With lead dioxide In dichloromethane at 40℃; for 0.166667h; | A 25.1% B 66.3% |
- 82126-20-3
1-ethoxycarbonyl-4-phenyl-1,4-dihydropyridine
A
- 939-23-1
p-phenylpyridine
B
- 623-53-0
ethyl methyl carbonate
| Conditions | Yield |
|---|---|
| With sodium methylate In methanol at 18℃; anodic oxidation (graphite-rod electrodes), 6 F/mol passed through the solution; | A 65% B n/a |
- 132819-55-7
2-Methyl-4-phenyl-4H-pyridine-1-carboxylic acid ethyl ester
A
- 15032-21-0
2-methyl-4-phenylpyridine
B
- 623-53-0
ethyl methyl carbonate
| Conditions | Yield |
|---|---|
| With sodium methylate In methanol at 18℃; anodic oxidation (graphite-rod electrodes); | A 60% B n/a |
- 631-22-1
diethyl dibromomalonate
- 110-83-8
cyclohexene
A
- 623-53-0
ethyl methyl carbonate
B
- 2415-79-4
7,7-dibromonorcarane
| Conditions | Yield |
|---|---|
| With sodium methylate at 0℃; | A n/a B 60% |
| With sodium methylate at 0℃; Mechanism; reactions under var. conditions; | A n/a B 60% |
Ethyl methyl carbonate Chemical Properties
Molecule structure of Ethyl methyl carbonate (CAS NO.623-53-0):
IUPAC Name: Ethyl methyl carbonate
Molecular Weight: 104.10452 g/mol
Molecular Formula: C4H8O3
Density: 0.997 g/cm3
Melting Point: -14.5 °C
Boiling Point: 107.5 °C at 760 mmHg
Flash Point: 26.7 °C
Index of Refraction: 1.378
Molar Refractivity: 24.1 cm3
Molar Volume: 104.4 cm3
Surface Tension: 25.9 dyne/cm
Enthalpy of Vaporization: 34.63 kJ/mol
Vapour Pressure: 27 mmHg at 25 °C
XLogP3-AA: 0.9
H-Bond Acceptor: 3
Rotatable Bond Count: 3
Exact Mass: 104.047344
MonoIsotopic Mass: 104.047344
Topological Polar Surface Area: 35.5
Heavy Atom Count: 7
Canonical SMILES: CCOC(=O)OC
InChI: InChI=1S/C4H8O3/c1-3-7-4(5)6-2/h3H2,1-2H3
InChIKey: JBTWLSYIZRCDFO-UHFFFAOYSA-N
Product Categories: CARBONATES
Ethyl methyl carbonate Uses
Ethyl methyl carbonate (CAS NO.623-53-0) is used in organic synthesis.
Ethyl methyl carbonate Safety Profile
Risk Statements: 10
R10:Flammable.
Safety Statements: 16
S16:Keep away from sources of ignition.
RIDADR: 3272
Ethyl methyl carbonate Specification
Ethyl methyl carbonate (CAS NO.623-53-0) is also named as carbonic acid, ethyl methyl ester ; Ethyl-methylcarbonat ; Carbonic acid, ethyl-, methyl ester ; Ethoxyacetic acid, methyl ester . Ethyl methyl carbonate (CAS NO.623-53-0) is colorless liquid. It is insoluble in water, soluble in ether, alcohol.
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