Basic Information | Post buying leads | Suppliers | Cas Database |
Name |
Ethylene glycol diglycidyl ether |
EINECS | 218-746-2 |
CAS No. | 2224-15-9 | Density | 1.178 g/cm3 |
PSA | 43.52000 | LogP | -0.18280 |
Solubility | N/A | Melting Point |
N/A |
Formula | C8H14O4 | Boiling Point | 266.774 °C at 760 mmHg |
Molecular Weight | 174.197 | Flash Point | 123.633 °C |
Transport Information | UN 2810 | Appearance | Clear yellow liquid |
Safety | 26-36/37/39 | Risk Codes | 38 |
Molecular Structure | Hazard Symbols | Xi | |
Synonyms |
Ethylene glycol diglycidyl ether;1,2-Bis(2,3-epoxypropoxy)ethane;1,2-Bis(glycidyloxy)ethane;2,2'-(1,2-Ethanediylbis(oxymethylene))bisoxirane;Diglycidylethylene glycol;Glycol diglycidyl ether;Oxirane, 2,2'-(1,2-ethanediylbis(oxymethylene))bis-;2,2'-(Ethylenebis(oxymethylene))bisoxirane;Ethylene glycol bis(2,3-epoxypropyl) ether; |
Article Data | 12 |
Conditions | Yield |
---|---|
With tetrabutyl-ammonium chloride; water; sodium hydroxide at 40℃; for 0.75h; | 89% |
With fluoroboric acid; trifluorormethanesulfonic acid; boron trifluoride at 40 - 65℃; for 5h; Temperature; Reagent/catalyst; Sonication; Inert atmosphere; Molecular sieve; Large scale; | 55.7% |
With potassium hydroxide; benzyltrioctylammonium chloride at 40℃; for 0.75h; | 54% |
1,10-Dichloro-4,7-dioxa-2,9-decanediol
ethylene glycol diglycidyl ether
Conditions | Yield |
---|---|
With sodium hydroxide Dehydrochlorination; | 40 g |
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate at 80℃; for 3h; | 99.3% |
ethylene glycol diglycidyl ether
Ethyl 1H,1H-perfluorooctanoxyacetate
1,1-dimethylhydrazine
Conditions | Yield |
---|---|
In methanol Heating; | 99% |
ethylene glycol diglycidyl ether
methyl 2,4,4,5,7,7,8,8,9,9,9-undecafluoro-2,5-bis(trifluoromethyl)-3,6-dioxanonanoate
1,1-dimethylhydrazine
Conditions | Yield |
---|---|
In methanol Heating; | 96% |
ethylene glycol diglycidyl ether
Methyl perfluoro-2,5,8,11-tetramethyl-3,6,9,12-tetraoxapentadecanoate
1,1-dimethylhydrazine
Conditions | Yield |
---|---|
In methanol Heating; | 96% |
Conditions | Yield |
---|---|
With tetrabutylammomium bromide at 110℃; under 7500.75 Torr; for 3h; | 94% |
With C42H44N8O6Zn(2+)*2Cl(1-) In neat (no solvent) at 100℃; under 750.075 Torr; for 24h; Kinetics; Pressure; Temperature; Autoclave; | 94.5% |
With C44H20AlCl9N4; bis(triphenylphosphine)iminium chloride In neat (no solvent) at 120℃; under 22502.3 Torr; for 1h; Autoclave; |
ethylene glycol diglycidyl ether
Methyl perfluoro-2,5,8-trimethyl-3,6,9-trioxadodecanoate
1,1-dimethylhydrazine
Conditions | Yield |
---|---|
In methanol Heating; | 94% |
Conditions | Yield |
---|---|
With Amberlyst-15 resin at 70℃; for 5h; | 93.2% |
ethylene glycol diglycidyl ether
methyl undecafluoro-2-methyl-3-oxahexanoate
1,1-dimethylhydrazine
Conditions | Yield |
---|---|
In methanol Heating; | 92% |
The Bis(1,2-epoxypropylether)ethanediol, with the CAS registry number 2224-15-9, is also known as Oxirane,2,2'-[1,2-ethanediylbis(oxymethylene)]bis-. It belongs to the product categories of Epoxy Diluents; Oxiranes; Simple 3-Membered Ring Compounds; Epoxide Monomers; Monomers; Polymer Science. Its EINECS number is 218-746-2. This chemical's molecular formula is C8H14O4 and molecular weight is 174.19. What's more, its systematic name is 2,2'-[1,2-Ethanediylbis(oxymethylene)]dioxirane. Its classification codes are: (1)Mutation data; (2)Skin / Eye Irritant; (3)TSCA Flag T [Subject to the Section 4 test rule under TSCA]. This chemical mixed with bisphenol A type epoxy resin can be used as low viscosity composite, impregnation liquid, adhesive and resin modifier.
Physical properties of Bis(1,2-epoxypropylether)ethanediol are: (1)ACD/LogP: -0.304; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -0.30; (4)ACD/LogD (pH 7.4): -0.30; (5)ACD/BCF (pH 5.5): 1.00; (6)ACD/BCF (pH 7.4): 1.00; (7)ACD/KOC (pH 5.5): 16.29; (8)ACD/KOC (pH 7.4): 16.29; (9)#H bond acceptors: 4; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 7; (12)Polar Surface Area: 43.52 Å2; (13)Index of Refraction: 1.476; (14)Molar Refractivity: 41.752 cm3; (15)Molar Volume: 147.899 cm3; (16)Polarizability: 16.552×10-24cm3; (17)Surface Tension: 45.83 dyne/cm; (18)Density: 1.178 g/cm3; (19)Flash Point: 123.633 °C; (20)Enthalpy of Vaporization: 48.442 kJ/mol; (21)Boiling Point: 266.774 °C at 760 mmHg; (22)Vapour Pressure: 0.014 mmHg at 25°C.
Preparation of Bis(1,2-epoxypropylether)ethanediol: this chemical can be prepared by chloromethyl-oxirane and at the temperature of 40 °C. This reaction will need reagent KOH with the reaction time of 45 min. This reaction will also need catalyst trioctylbenzylammonium chloride. The yield is about 54%.
Uses of Bis(1,2-epoxypropylether)ethanediol: it can be used to produce 1,4-dioxa-8,12-diaza-cyclopentadecane-6,14-diol by heating. It will need reagent NaH and solvent H2O. The yield is about 82%.
When you are using this chemical, please be cautious about it as the following:
It is irritating to skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. When using it, you need wear suitable protective clothing, gloves and eye/face protection.
You can still convert the following datas into molecular structure:
(1)SMILES: O(CC1OC1)CCOCC2OC2
(2)Std. InChI: InChI=1S/C8H14O4/c1(9-3-7-5-11-7)2-10-4-8-6-12-8/h7-8H,1-6H2
(3)Std. InChIKey: AOBIOSPNXBMOAT-UHFFFAOYSA-N
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LD50 | oral | 460mg/kg (460mg/kg) | "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 775, 1986. | |
rat | LD50 | oral | 2500uL/kg (2.5mL/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: ATAXIA GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS | National Technical Information Service. Vol. OTS0571709. |