Journal of the American Chemical Society p. 4969 - 4973 (1987)
Update date:2022-08-03
Topics:
Nakamura, Norinaga
Nojima, Masatomo
Kusabayashi, Shigekazu
Ozonolysis of diene 1 in carbon tetrachloride gave exclusively the keto ester 2, while in methanol the keto olefin 17 was the major product.The behavior of model vinyl ethers 3a,b has revealed that a mechanism involving intramolecular oxygen atom transfer from the carbonyl oxide moiety to a methoxyvinyl group is the most probable for the keto ester formation from diene 1.
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