Relative donor properties of sp3 and sp2 hybridised phosphorus atoms of the azadiphosphetine ring systems (R = Et3C, R' = But) towards transition metals

DOI: 10.1016/0022-328X(90)85113-D

Source and publish data:

Journal of Organometallic Chemistry p. C89 - C92 (1990)

Update date:2022-09-26

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Authors:

Matos, Robson

Meidine, Mohamed F.

Nixon, John F.

Passos, Bernadette F. Trigo

Niecke, Edgar

Barion, Detlef

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Article abstract of DOI:10.1016/0022-328X(90)85113-D

Different types ligating behaviour of the <*> ring system are reported; the sp² hybridised phosphorus is the donor atom in Pt(0), W(0) and Rh(I) complexes, whereas ligation of the sp³ hybridised phosphorus atom is preferred by Pd(II)

Full text of DOI:10.1016/0022-328X(90)85113-D

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