Journal of the Chemical Society. Chemical communications p. 1253 - 1255 (1991)
Update date:2022-07-31
Topics: Enantioselectivity Catalytic hydrogenation Complexes Effect Rhodium Anchored Support Remarkable
Corma, A.
Iglesias, M.
Pino, C. del
Sanchez, F.
Rh-complexes with N-based chiral ligands, when anchored on a modified USY-zeolite which contains profuse supermicropores, produce a remarkable increase of enantioselectivity (>95percent) in the hydrogenation of N-acyldehydrophenylalanine derivatives and represent a truly heterogeneous counterpart of the homogeneous organometallic catalysts.
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