New Rhodium Complexes anchored on Modified USY Zeolites. A Remarkable Effect of the Support on the Enantioselectivity of Catalytic Hydrogenation of Prochiral Alkenes

DOI: 10.1039/c39910001253

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1253 - 1255 (1991)

Update date:2022-07-31

Topics: Enantioselectivity Catalytic hydrogenation Complexes Effect Rhodium Anchored Support Remarkable

Authors:

Corma, A.

Iglesias, M.

Pino, C. del

Sanchez, F.

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Article abstract of DOI:10.1039/c39910001253

Rh-complexes with N-based chiral ligands, when anchored on a modified USY-zeolite which contains profuse supermicropores, produce a remarkable increase of enantioselectivity (>95percent) in the hydrogenation of N-acyldehydrophenylalanine derivatives and represent a truly heterogeneous counterpart of the homogeneous organometallic catalysts.

Full text of DOI:10.1039/c39910001253

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