POLYSULFOXIDES AS NEW TYPE OF PHASE TRANSFER CATALYSTS IN TWO PHASE ALKYLATION

DOI: 10.1246/cl.1982.1421

Source and publish data:

Chemistry Letters p. 1421 - 1424 (1982)

Update date:2022-08-04

Topics:

Authors:

Furukawa, Naomichi

Imaoka, Koji

Fujihara, Hisashi

Oae, Shigeru

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Article abstract of DOI:10.1246/cl.1982.1421

Tetrakis(hexylsulfinylmethyl)methane(I) and related compounds and polysulfides of crown thiaether(IV) were prepared and found to be used as effective catalysts in the binary phase alkylation of phenylacetonitrile(V) and phenylacetone(VI) with alkyl halides to afford selectively the corresponding monoalkylated products in high yields.

Full text of DOI:10.1246/cl.1982.1421

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