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New Journal of Chemistry
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COMMUNICATION
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Furthermore, the immobilization of catalysts on polymer
support has successfully isolated catalytic sites in Cu-POP and
reduced the potential catalyst deactivation.28
In summary, a new class of heterogeneous catalyst Cu-POP
was prepared by integrating (bpy)Cu(II)Cl2 moiety in porous
organic polymer support fabricated from alkyne–azide
cycloaddition between 5,5′-diethynyl-2,2′-bipyridine and
tetra(4-azidophenyl)methane, and the heterogeneous catalytic
oxidation of various olefins was exploited. Cu-POP showed good
catalytic activities towards various olefins, in comparison to its
2012, 112, 1105-1125.
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15 Z. Xie, C. Wang, K. E. deKrafft, W. Lin, J. Am. Chem. Soc., 2011,
homogeneous
counterpart.
Remarkably,
the
new
133, 2056-2059.
heterogeneous catalyst displayed excellent reusability without
losing its activity, even after 5 recycle tests, and we successfully
demonstrated the use of one batch of Cu-POP for various
olefins by simply filtering and washing the catalyst. Due to
successful site isolation via the immobilization of catalysts on
porous organic polymer support, the degradation of catalytic
sites by generating catalytically inactive aggregated species was
effectively inhibited, and highly stable catalyst was achieved.
16 (a) A. B. Soliman, M. H. Hassan, A. A. Abugable, S. G.
Karakalos, M. H. Alkordi, ChemCatChem. 2017, 9, 2946-2951.
(b) H. Li, C. Li, J. Chen, L. Liu, Q. Yang, Chem. Asian J. 2017, 12,
1095-1103. (c) H. Ma, H. Ren, X. Zou, S. Meng, F. Suna, G. Zhu,
Polym. Chem., 2014, 5, 144-152.
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Bordiga, J. Mater. Chem. A., 2017, 5, 372-383.
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Zhao, C.-K. Tsung, J. Am. Chem. Soc., 2012, 134, 14345-14348.
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23 J. Sun, Q. Kan, Z. Li, G. Yu, H. Liu, X. Yang, Q. Huo and J. Guan,
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Conflicts of interest
There are no conflicts to declare.
Acknowledgements
This work was financially supported by the Research Foundation
Program of Korea (KNRF-2019R1A2C1088688).
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