Molecules p. 4511 - 4525 (2010)
Update date:2022-08-29
Topics:
Monopoli, Antonio
Nacci, Angelo
Calo, Vincenzo
Ciminale, Francesco
Cotugno, Pietro
Mangone, Annarosa
Giannossa, Lorena Carla
Azzone, Pietro
Cioffi, Nicola
Palladium nanoparticles have been electrochemically supported on zirconium oxide nanostructured powders and all the nanomaterials have been characterized by several analytical techniques. The Pd/ZrO2 nanocatalyst is demonstrated to be a very efficient catalyst in Heck, Ullmann, and Suzuki reactions of aryl halides in water. The catalyst efficiency is attributed to the stabilization of Pd nanophases provided by tetra(alkyl)- ammonium hydroxide, which behaves both as base and PTC (phase transfer catalyst) agent.
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