at room temperature with stirring. The solution immediately
turned deep red. It was filtered and diffused with dry benzene and
allowed to evaporate at room temperature. Dark red X-ray quality
rectangular-shaped crystals of 1 appeared in about one day. Yield
7 I. Sondi and B. Salopek-Sondi, J. Colloid Interface Sci., 2004, 275, 177.
8
9
A. D. Russell and W. B. Hugo, Prog. Med. Chem., 1994, 31, 351.
H. I. Scheinberg, Metals and their Compounds in the Environment:
Occurrence, Analysis and Biological Relevance, ed. E. Merian, VCH,
New York, 1991.
~
50%. Anal. calcd for C15
H
22
F
3
N
3
O
5
SAg found: C 34.4, H 4.3,
10 (a) H. T. Ratte, Environ. Toxicol. Chem., 1999, 18, 89; (b) M. R. Ganjali,
P. Norouzi, T. Alizadeh and M. Adib, J. Braz. Chem. Soc., 2006, 17,
N 8.1% and requires: C 34.5, H 4.2, N 8.0%). m/z 455.12 ([HL +
1
217; (c) X. B. Zhang, Z. X. Han, Z. H. Fang, G. L. Shen and R. Q.
+
+
Ag] , 100%) and 562.21 ([HL + 2Ag] , 50%) (ESI).
Compound {[Ag (LL) (NO ]·(H O)} (2). This complex was
synthesized following a reported procedure. Anal. calcd for
found C 52.6, H 5.8, N 15.6% and requires C
Yu, Anal. Chim. Acta, 2006, 562, 210; (d) M. Kazuyuki, H. Nobuo,
K. Takatoshi, K. Yuriko, H. Osamu, I. Yashihisa and S. Kiyoko, Clin.
Chem., 2001, 47, 763; (e) H. Q. Peng, B. W. Brooks, R. Chan, O. Chyan
and T. W. L. Point, Chemosphere, 2002, 46, 1141; (f) A. T. Wan, R. A.
Conyers, C. J. Coombs and J. P. Masterton, Clin. Chem., 1991, 37, 1683.
11 (a) K. Rurack, M. Kollmannsberger, U. Resch-Genger and J. Daub,
J. Am. Chem. Soc., 2000, 122, 968; (b) L. Liu, D. Zhang, G. Zhang, J.
Xiang and D. Zhu, Org. Lett., 2008, 10, 2271; (c) S. Iyoshi, M. Taki
and Y. Yamamoto, Inorg. Chem., 2008, 47, 3946; (d) J. Raker and T. E.
Glass, J. Org. Chem., 2001, 66, 6505; (e) H. Tong, L. Wang, X. Jing
and F. Wang, Macromolecules, 2002, 35, 7169; (f) L. Jia, Y. Zhang, X.
Guo and X. Qian, Tetrahedron Lett., 2004, 45, 3969; (g) J. Ishikawa,
H. Sakamoto, S. Nakao and H. Wada, J. Org. Chem., 1999, 64, 1913;
2
3
3
)
2
2
14
C
54
H
68Ag
2
N
14
O
7
+
5
2.3, H 5.5, N 15.8%). m/z 401.08 ([LL + Ag] , 95%) and 501.03
+
(
[LL + 2Ag] , 45%) (ESI).
Acknowledgements
Financial support received from DRDO & DST, New Delhi, India
(
h) M. Schmittel and H. Lin, Inorg. Chem., 2007, 46, 9139; (i) S. Xu,
(
to P. K. B.), is gratefully acknowledged. D. R. and K. K. S.
W. Li and K. C. Chen, Chin. J. Chem., 2007, 25, 778; (j) J. Ishikawa, H.
Sakamoto and H. Wada, J. Chem. Soc., Perkin Trans. 2, 1999, 1273.
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H.-K. Zhang and K. Li, J. Am. Chem. Soc., 2003, 125, 2884; (c) A.
Coskun and E. U. Akkaya, J. Am. Chem. Soc., 2005, 127, 10464; (d) P.
Singh and S. Kumar, Tetrahedron, 2006, 62, 6379; (e) K. Shamsipur, M.
Alizadeh, M. Hosseini, C. Caltagirone and V. Lippolis, Sens. Actuators
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66, 6505.
thank CSIR for SRF, E. S. S. I. thanks CSIR for JRF. We thank
Prof. Anindya Datta for time-resolved fluorescence and solid-state
fluorescence data.
1
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