Synthesis p. 790 - 792 (1986)
Update date:2022-08-16
Topics:
Coutrot, Philippe
Ghribi, Abdellaziz
A general synthesis of α-branched α,β-unsaturated carboxylic acids is described.A Horner reaction of 2-diethoxyphosphorylalkanoic acid dianions (lithium α-lithiocarboxylates) with carbonyl compounds is used.The reaction is applied to the stereoselective synthesis of Manicone.
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Doi:10.1002/cctc.202000651
(2020)Doi:10.1002/aoc.2960
(2013)Doi:10.1021/ja00833a031
(1974)Doi:10.1021/acs.joc.9b00055
(2019)Doi:10.1039/cc9960000341
(1996)Doi:10.1039/d0ta10607k
(2021)