Synthesis p. 790 - 792 (1986)
Update date:2022-08-16
Topics:
Coutrot, Philippe
Ghribi, Abdellaziz
A general synthesis of α-branched α,β-unsaturated carboxylic acids is described.A Horner reaction of 2-diethoxyphosphorylalkanoic acid dianions (lithium α-lithiocarboxylates) with carbonyl compounds is used.The reaction is applied to the stereoselective synthesis of Manicone.
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