Helvetica Chimica Acta p. 105 - 112 (1984)
Update date:2022-08-11
Topics:
Mueller, Paul
Joly, Daniel
Mermoud, Francois
cis- and trans-(3,6-D2)-1,4-cyclohexadienes 1a and 1b have been synthesized from cis-3,4-dichlorocyclobutene (5).Aromatization to benzene with DDQ is cis-stereospecific with an uncertainty of 5percent.This results is discussed in relation to concerted or stepwise mechanisms for aromatization of 1,4-dihydroaromatics with 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ).
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