Stereochemistry and mechanism of the ligand-coupling reaction of an optically active acetylacetonato(?-allyl)palladium complex

DOI: 10.1016/0022-328X(88)80511-4

Source and publish data:

Journal of Organometallic Chemistry p. 261 - 264 (1988)

Update date:2022-08-30

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Authors:

Hayashi, Tamio

Yamamoto, Akihiro

Ito, Yoshihiko

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Article abstract of DOI:10.1016/0022-328X(88)80511-4

The reaction of optically active acetylacetonato(1-methyl-3-phenyl-?-allyl)palladium(II) with triphenylphosphine in THF gave <1-((E)-styryl)ethyl>acetylacetone with inversion of configuration, which indicates that the acetylacetonate anion attacked the ?-allyl carbon of a cationic phosphine complex from the side opposite to palladium.

Full text of DOI:10.1016/0022-328X(88)80511-4

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Article Doi

Stereochemistry and mechanism of the ligand-coupling reaction of an optically active acetylacetonato(?-allyl)palladium complex

DOI: 10.1016/0022-328X(88)80511-4

Source and publish data:

Authors:

Article abstract of DOI:10.1016/0022-328X(88)80511-4

Full text of DOI:10.1016/0022-328X(88)80511-4

Products guided by the article

R&D Labs maybe for 118578-64-6

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