Tetrahedron Letters p. 1775 - 1776 (1986)
Update date:2022-08-16
Topics:
Cristau, Henri-Jean
Torreilles, Eliane
Morand, Philippe
Christol, Henri
The bisphosphonium bichromate 1, appears as particularly mild and selective for the oxidation of primary or secondary alcohols.It performs the oxidation of primary alcohols into aldehydes without further oxidation in acid and without double-bond isomerisation or migration for such alcohols as geraniol; it allows also the fully selective oxidation of benzylic or allylic alcohols versus aliphatic alcohols.
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(1987)