Journal of Organometallic Chemistry (2019)
Update date:2022-08-16
Topics:
Wang, Zhe
Yu, Shen-Luan
Wei, Zan-Bin
An, Dong-Li
Li, Yan-Yun
Gao, Jing-Xing
Novel nickel(II) complexes 1 and 2 could be conveniently prepared using PxNy-type ligands and easily available NiCl2·6H2O as a starting material. Furthermore, we obtained the single crystals suitable for X-ray diffraction to confirm the structure of these two nickel(II) complexes. With the well-designed nickel(II) complex, the hydrogenation of a wide range of ketones proceeded smoothly under relative mild reaction conditions, affording the corresponding alcohols with high isolated yields.
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