Angewandte Chemie - International Edition p. 8851 - 8856 (2019)
Update date:2022-08-11
Topics:
Peil, Sebastian
Guthertz, Alexandre
Biberger, Tobias
Fürstner, Alois
The unusual geminal hydrogenation of a propargyl alcohol derivative with [CpXRuCl] as the catalyst entails formation of pianostool ruthenium carbenes in the first place; these reactive intermediates can be intercepted with tethered alkenes to give either cyclopropanes or cyclic olefins as the result of a formal metathesis event. The course of the reaction is critically dependent on the substitution pattern of the alkene trap.
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