Journal of Organic Chemistry p. 1429 - 1432 (1990)
Update date:2022-08-05
Topics:
Szymoniak, Jan
Besancon, Jack
Dormond, Alain
Moise, Claude
The synthesis of two new heterodifunctional ligands for organotransition-metal chemistry, Ph2P(CH2)nC5Me4H (n=0, 2), is described.Both compounds are derived from the same intermediate, lithium tetramethylcyclopentadienide.For n=2 the ligand is obtained by a one-pot reaction including two successive nucleophilic substitutions.
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