Journal of Physical Chemistry p. 748 - 751 (1994)
Update date:2022-08-30
Topics:
Novak, Igor
Ng, Siu Choon
Fang, Jiye
Mok, Chup Yew
Huang, Hsing Hua
He I and He II photoelectron spectra of all isomeric mono- and diethynylthiophenes were recorded.The electronic structure was analyzed and spectra assigned on the basis of empirical considerations and semiempirical MO calculations.The spectra indicate various interactions taking place between thiophene ? and ethynyl ? orbitals.The relationship between deduced electronic structure and formation of novel polymer materials is discussed.
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