Journal of Organic Chemistry p. 7789 - 7798 (2018)
Update date:2022-08-11
Topics:
Wang, Rongkang
Jiang, Lvqi
Yi, Wenbin
Metal-free trifluoroethylthiolation with fluorinated sulfinate salt NaSO2CH2CF3 under reductive conditions has been developed. The strategy enables the installation of the SCH2CF3 moiety efficiently to form a number of unexplored stable trifluoroethylthiolated heterocycles, arenes, and thiols, which have the potential to be a new series of fluorine-containing chemical entities for medicinal chemists.
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