Journal of the American Chemical Society
Article
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covalent template-directed oligomerization reactions compared
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ASSOCIATED CONTENT
Compounds by Directed Synthesis. Angew. Chem., Int. Ed. Engl.
1964, 3, 546−547.
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* Supporting Information
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macrocyclic hosts containing convergent hydroxy groups. J. Chem.
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The Supporting Information is available free of charge on the
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Materials and methods, synthetic procedures and
compound characterization, and details of LCMS
methods used for reaction monitoring (PDF)
(17) Zimmerman, S. C.; Zharov, I.; Wendland, M. S.; Rakow, N. A.;
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AUTHOR INFORMATION
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(18) Hiratani, K.; Kaneyama, M.; Nagawa, Y.; Koyama, E.; Kanesato,
M. Synthesis of [1]Rotaxane via Covalent Bond Formation and Its
Unique Fluorescent Response by Energy Transfer in the Presence of
Lithium Ion. J. Am. Chem. Soc. 2004, 126, 13568−13569.
(19) Kawai, H.; Umehara, T.; Fujiwara, K.; Tsuji, T.; Suzuki, T.
Dynamic covalently bonded rotaxanes cross-linked by imine bonds
between the axle and ring: inverse temperature dependence of subunit
mobility. Angew. Chem., Int. Ed. 2006, 45, 4281−4286.
(20) Lin, N.-T.; Lin, S.-Y.; Lee, S.-L.; Chen, C.-h.; Hsu, C.-H.;
Hwang, L.-P.; Xie, Z.-Y.; Chen, C.-H.; Huang, S.-L.; Luh, T.-Y. From
polynorbornene to the complementary polynorbornene by replica-
tion. Angew. Chem., Int. Ed. 2007, 46, 4481−4485.
Corresponding Author
ORCID
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Funding
European Research Council (ERC-2012-AdG 320539-duplex)
and the Herchel Smith Fund for funding.
Notes
The authors declare no competing financial interest.
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(21) Schweez, C.; Shushkov, P.; Grimme, S.; Hoger, S. Synthesis and
Dynamics of Nanosized Phenylene-Ethynylene-Butadiynylene Rotax-
anes and the Role of Shape Persistence. Angew. Chem., Int. Ed. 2016,
55, 3328−3333.
(22) Steemers, L.; Wanner, M. J.; Lutz, M.; Hiemstra, H.; Van
Maarseveen, J. H. Synthesis of spiro quasi[1]catenanes and quasi[1]-
rotaxanes via a templated backfolding strategy. Nat. Commun. 2017, 8,
15392.
ACKNOWLEDGMENTS
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We thank the ERC (ERC-2012-AdG 320539-duplex) and the
Herchel Smith Fund for funding.
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