Bulletin of the Chemical Society of Japan p. 942 - 944 (1989)
Update date:2022-08-28
Topics:
Yamashita, Mitsuji
Naoi, Manabu
Imoto, Hiroyuki
Oshikawa, Tatsuo
Diphenylphosphinite derivatives of carbohydrates (L-rhamnose, D-mannitol, and cellulose), which have asymmetric centers on the skeletons were synthesized.Asymmetric hydrogenations of prochiral substrates using rhodium catalysts with the prepared chiral phosphinite ligand were carried out to obtain chiral substances in 8-78percent optical yield.
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