Journal of Organometallic Chemistry p. 61 - 69 (2014)
Update date:2022-08-12
Topics:
Islam, Sk Manirul
Ghosh, Kajari
Molla, Rostam Ali
Roy, Anupam Singha
Salam, Noor
Iqubal, Md Asif
Polymer anchored cobalt(II) catalyst was synthesized and characterized. The solid catalyst was characterized by fourier transform infrared spectroscopy (FT-IR), UV-vis diffuse reflectance spectroscopy (DRS), thermogravimetric analysis (TGA) and scanning electron microscope (SEM). The catalytic activity of the complex was investigated for the oxidative functionalization of alkyl aromatics to benzylic ketones using O2 (1 atm) with 1 mmol H2O2. The oxidation of organic compounds with carbon-carbon double bond with molecular oxygen under atmospheric pressure in the presence of this catalyst has also been studied. Oxidation of alkenes, cycloalkenes and terpenes gave corresponding epoxy derivatives. The developed catalyst can be facilely recovered and reused six times without significant decrease in its activity and selectivity.
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