SYNTHESIS AND NMR SPECTRA OF 2,2,2,-TRIDEUTERIOETHYLARSINE AND 2,2,2-TRIDEUTERIOETHYLCYCLOPENTAARSINE

Article abstract of DOI:10.1016/S0022-328X(00)81950-6

Pentakis(2,2,2-trideuterioethyl)cyclopentaarsine (PDECA) was synthesized by the reaction of 2,2,2-trideuterioethylarsine with dibenzylmercury.Variable temperature NMR spectra in C6D6 are interpreted in terms of fast pseudorotation.NMR and mass spectra and synthesis of 2,2,2-trideuterioethylarsine are also described.