FORMATION AND REARRANGEMENT OF TRICYCLO4,10>UNDECA-2,4,6,8,TETRAEN-10-OL, NOVEL PATHWAY FROM BICYCLOUNDECA-1(10),2,4,8-TETRAEN-11-ONE TO 4-METHYLAZULENE

DOI: 10.1016/S0040-4039(00)88316-1

Source and publish data:

Tetrahedron Letters p. 4261 - 4264 (1983)

Update date:2022-08-11

Topics:

Authors:

Fujise, Yutaka

Morishima, Takashi

Namiwa, Kimiyoshi

Shiokawa, Toshihiro

Fukazawa, Yoshimasa

Ito, Sho

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Article abstract of DOI:10.1016/S0040-4039(00)88316-1

Abstract: By the action of LDA bicyclo<4.4.1>undeca-1(10),2,4,8-tetraen-11-one was found to undergo transannular cyclization to form a unique tricyclic hydroxydihydroazulene which cleaves a C-C bond by electrocyclic process and eventually give 4-methylazulene.

Full text of DOI:10.1016/S0040-4039(00)88316-1

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