Please d oC hn eo mt Ca do mj u ms t margins
Page 4 of 5
COMMUNICATION
Journal Name
other words, TPES-M and TPES-P displayed right- and left-handed
CPL respectively, whose handednesses are opposite to those of the
nanotubes. This further proved that there is no direct relationship
between the chirality at the molecular level and the handedness at
the nanolevel. The glum values of TPES-M and TPES-P were
N. Zigon and N. Avarvari, Chem. Rev., 2019, 119, 8435.
DOI: 10.1039/C9CC06055C
5
(a) E. Yashima, N. Ousaka, D. Taura, K. Shimomura, T. Ikai and
K. Maeda, Chem. Rev., 2016, 116, 13752; (b) T. Ikai, T.
Yoshida, S. Awata, Y. Wada, K. Maeda, M. Mizuno and T. M.
Swager, ACS Macro Lett., 2018, 7, 364; (c) L. Yang, Y. Zhang, X.
Zhang, N. Li, Y. Quan and Y. Cheng, Chem. Commun., 2018, 54,
-3
-3
calculated to be about –0.6 × 10 and +1.6 × 10 at 500 nm,
respectively (Fig. 3d), which were comparable to most of the CPL-
9
663; (d) T. Yamada, K. Nomura and M. Fujiki,
Macromolecules, 2018, 51, 2377.
-4
-2 10,11
active materials based on the AIEgens (|glum| = 10 – 10 )
.
6
7
(a) D. Zhao, H. He, X. Gu, L. Guo, K. S. Wong, J. W. Y. Lam and
B. Z. Tang, Adv. Opt. Mater., 2016, 4, 534; (b) J. Yan, F. Ota, B.
A. San Jose and K. Akagi, Adv. Funct. Mater., 2017, 27,
In conclusion, we have successfully prepared two single-
handed helical TPE–Silica nanotubes, TPES-M and TPES-P,
using BTSTPE as a single-source precursor and self-assemblies
of chiral LMWGs as the templates via a supramolecular
templating approach. It was found that the chirality had
transferred from the templates to the inorganic- organic
hybrid nanostructures. TPES-M and TPES-P exhibited CPL
1
604529; (c) X. Li, Q. Li, Y. Wang, Y. Quan, D. Chen and Y.
Cheng, Chem. Eur. J., 2018, 24, 12607; (d) X. Gao, X. Qin, X.
Yang, Y. Li and P. Duan, Chem. Commun., 2019, 55, 5914.
(a) J. Kumar, T. Nakashima and T. Kawai, J. Phys. Chem. Lett.,
2
015, 6, 3445; (b) Y. Wang, X. Li, F. Li, W. Sun, C. Zhu and Y.
Cheng, Chem. Commun., 2017, 53, 7505; (c) D. Yang, P. Duan,
L. Zhang and M. Liu, Nat. Commun., 2017, 8, 15727; (d) T.
Goto, Y. Okazaki, M. Ueki, Y. Kuwahara, M. Takafuji, R. Oda
and H. Ihara, Angew. Chem. Int. Ed., 2017, 56, 2989; (e) X. Jin,
D. Yang, Y. Jiang, P. Duan and M. Liu, Chem. Commun., 2018, 54,
-3
-3
activities with the glum values of –0.6 × 10 and +1.6 × 10
respectively, and fluorescence quantum yields of 26.2% and
1.2% respectively. Additionally, they possessed high thermal
2
stability. These properties make them promising candidates
for applications in chemical sensing, CPL lasers, and
photoelectronic devices. To the best of our knowledge, this is a
first example of CPL-active inorganic-organic hybrid
4513; (f) F. Wang, W. Ji, P. Yang and C.-L. Feng, ACS Nano.,
2019, 13, 7281; (g) L. Ji, Y. Sang, G. Ouyang, D. Yang, P. Duan,
Y. Jiang and M. Liu, Angew. Chem. Int. Ed., 2019, 58, 844.
J. B. Birks, Photophysics of Aromatic Molecules, Wiley, New
York, 1970.
8
9
nanostructures
with
single-handed helical morphologies.
J. Mei, N. L. C. Leung, R. T. K. Kwok, J. W. Y. Lam and B. Z.
Tang, Chem. Rev., 2015, 115, 11718.
Furthermore, this work provides a simple method for
fabricating inorganic-organic hybrid functional nanomaterials 10 (a) J. Roose, B. Z. Tang and K. S. Wong, Small, 2016, 12, 6495;
(b) H. Li, B. S. Li and B. Z. Tang, Chem.-Asian J., 2019, 14, 674.
with efficient CPL performance.
1
1 (a) J. Liu, H. Su, L. Meng, Y. Zhao, C. Deng, J. C. Y. Ng, P. Lu, M.
Faisal, J. W. Y. Lam, X. Huang, H. Wu, K. S. Wong and B. Z.
Tang, Chem. Sci., 2012, 3, 2737; (b) H. Li, S. Xue, H. Su, B.
Shen, Z. Cheng, J. W. Y. Lam, K. S. Wong, H. Wu, B. S. Li and B.
Z. Tang, Small, 2016, 12, 6593; (c) J.-B. Xiong, H.-T. Feng, J.-P.
Sun, W.-Z. Xie, D. Yang, M. Liu and Y.-S. Zheng, J. Am. Chem.
Soc., 2016, 138, 11469; (d) H. Qu, Y. Wang, Z. Li, X. Wang, H.
Fang, Z. Tian and X. Cao, J. Am. Chem. Soc., 2017, 139, 18142;
This work was supported by the National Nature Science
Foundation of China (21875152, 51673141 and 21574095),
and the Priority Academic Program Development of Jiangsu
High Education Institutions (PAPD). H. Li acknowledges the
financial supports from Jiangsu Planned Projects for
Postdoctoral Research Funds (1501023B) and China
Postdoctoral Science Foundation (2016M591906). We thank
Mr. Maoxing Yu, Mr. Ruishan Huang and Prof. Zujin Zhao at the
(
e) H.-T. Feng, Y.-X. Yuan, J.-B. Xiong, Y.-S. Zheng and B. Z.
Tang, Chem. Soc. Rev., 2018, 47, 7452.
State Key Laboratory of Luminescent Materials and Devices in 12 (a) J. Hu and Y. Yang, Gels, 2017, 3, 2; (b) Y. Li and Y. Yang,
Chem. Rec., 2017, 17, 1; (c) Y. Li, S. Wang, M. Xiao, M. Wang,
Z. Huang, B. Li and Y. Yang, Nanotechnology, 2013, 24,
South China University of Technology for their kind help with
the CPL and fluorescence quantum yield measurements.
0
35603.
1
1
1
3 M. Murata, M. Ishikura, M. Nagata, S. Watanabe and Y.
Masuda, Org. Lett., 2002, 4, 1843.
Conflicts of interest
There are no conflicts to declare.
4 Y. Yang, M. Suzuki, S. Owa, H. Shirai and K. Hanabusa, J. Am.
Chem. Soc., 2007, 129, 581.
5 F.-W. Hou, L.-M. Wu, Y.-M. Guo, Y. Li and B.-Z. Li, Chin. Chem.
Lett., 2013, 24, 770.
1
6 (a) X. Wan, X. Pei, H. Zhao, Y. Chen, Y. Guo, B. Li, K. Hanabusa
and Y. Yang, Nanotechnology, 2008, 19, 315602; (b) H. Huo, Y.
Li, Y. Yuan, S. Lin, B. Li, M. Wang and Y. Yang, Chem. Asian J.,
Notes and references
1
M. C. Heffern, L. M. Matosziuk and T. J. Meade, Chem. Rev.,
014, 114, 4496.
2
2
014, 9, 2866.
2
(a) J. Han, S. Guo, H. Lu, S. Liu, Q. Zhao and W. Huang, Adv.
Opt. Mater., 2018, 6, 1800538; (b) F. Zinna, S. Voci, L. Arrico,
E. Brun, A. Homberg, L. Bouffier, T. Funaioli, J. Lacour, N. Sojic
and L. D. Bari, Angew. Chem. Int. Ed., 2019, 58, 6952; (c) X.
Zhang, Y. Zhang, H. Zhang, Y. Li, Y. Quan and Y. Cheng, Org.
Lett., 2019, 21, 439.
1
1
7 (a) H. Huo, S. Wang, S. Lin, Y. Li, B. Li and Y. Yang, J. Mater.
Chem. A, 2014, 2, 333; (b) X. Wu, S. Ji, Y. Li, B. Li, X. Zhu, K.
Hanabusa and Y. Yang, J. Am. Chem. Soc., 2009, 131, 5986.
8 (a) J. Mei, Y. Hong, J. W. Y. Lam, A. Qin, Y. Tang and B. Z. Tang,
Adv. Mater., 2014, 26, 5429; (b) D. Li and J. Yu, Small, 2016,
1
2, 6478.
3
4
(a) M. Sugimoto, X.-L. Liu, S. Tsunega, E. Nakajima, S. Abe, T.
Nakashima, T. Kawai and R.-H. Jin, Chem. Eur. J., 2018, 24,
6
519; (b) N. Shi, R. Wang, X. Wang, J. Tan, Y. Guan, Z. Li, X.
Wan and J. Zhang, Chem. Commun., 2019, 55, 1136.
(a) E. M. Sánchez-Carnerero, A. R. Agarrabeitia, F. Moreno, B.
L. Maroto, G. Muller, M. J. Ortiz and S. de la Moya, Chem. Eur.
J., 2015, 21, 13488; (b) Y. Nojima, M. Hasegawa, N. Hara, Y.
4
| J. Name., 2012, 00, 1-3
This journal is © The Royal Society of Chemistry 20xx
Please do not adjust margins