Metal-catalyzed ylide formation and [2,3] sigmatropic rearrangement of allyl sulfides with trimethylsilyldiazomethane

DOI: 10.1016/S0040-4039(99)00112-4

Source and publish data:

Tetrahedron Letters p. 1617 - 1620 (1999)

Update date:2022-08-11

Topics:

Authors:

Carter, David S.

Van Vranken, David L.

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Article abstract of DOI:10.1016/S0040-4039(99)00112-4

Trimethylsilyldiazomethane is compared with ethyl diazoacetate for the rhodium, copper, and cobalt catalyzed formation and [2,3] rearrangement of allylsulfonium ylides. At room temperature, the reaction can be carried out using the allyl sulfide as the li

Full text of DOI:10.1016/S0040-4039(99)00112-4

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