Journal of Chemical Physics p. 4088 - 4097 (1989)
Update date:2022-08-11
Topics:
Yetter, Richard A.
Rabitz, Herschel
Dryer, Frederick L.
Maki, Robert G.
Klemm, R. Bruce
Novel modeling and sensitivity analysis techniques are used with experimental data obtained from discharge flow-resonance fluorescence experiments to evaluate the product branching ratio of OH + H2CO.Two channels are considered: the H-atom abstraction reaction (R2) to form HCO and H2O; and the addition reaction ( R 17 ) followed by rearrangement and decomposition to form HCOOH and H.The rate constant values obtained at 298 K are kR2 = (7.75+/-1.24) X 10-12 cm3/molecule s and kR17= (0.2-0.2+0.8) X 10-12 cm3/molecule s.The results demonstrate that the reaction proceeds almost exclusively via the H-atom abstraction pathway.
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