Journal of Physical Chemistry p. 2993 - 2995 (1980)
Update date:2022-08-25
Topics:
Jalenak, W. A.
Nogar, N. S.
The multiphoton-induced decomposition of 1-chloro-1-fluoroethylene (CH2CClF) and the effect of laser fluence upon the decomposition pathways has been investigated by using a pulsed TEA CO2 laser operating at 10.632 μm.CH2CClF has been found to decompose via two competing pathways, yielding either HF and HCCCl or HCl and HCCf.The decomposition reactions have been followedin real time by monitoring the IR fluorescence from the vibrationally excited HF and HCl.Variation of the laser fluence causes the HF/HCl product ratio to change.This change is explained in terms of a competition between the reaction pathways and the optical pumping rate.
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