Journal of the Chemical Society. Chemical communications p. 164 - 165 (1981)
Update date:2022-08-16
Topics:
Pelter, Andrew
Rupani, Pushpa
Stewart, Peter
Lithium trialkylalkynylborates react in a stereoselective fashion with benzo-1,3-dithiolium fluoroborate to give vinylboranes which on oxidation yield protected 3-oxo-aldehydes and on hydrolysis give protected αβ-unsaturated aldehydes; the hydrolysis is highly selective giving rise eventually to stereospecifically defined αβ-unsaturated aldehydes by a novel process.
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