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Journal of the American Chemical Society
Synthetic and spectroscopic methods, full MO diagrams,
Cartesian coordinates, and CIF for [2] . This material is
available free of charge via the Internet at
http://pubs.acs.org.
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AUTHOR INFORMATION
Corresponding Authors
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010, 327 (5967), 794-795.
Sharma, S. K.; May, P. S.; Jones, M. B.; Lense, S.;
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Hardcastle, K. I.; MacBeth, C. E. Chem. Commun. 2011, 47 (6), 1827-
829.
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50 (51), 12140-12142.
For examples of M-O
Present Address
Department of Natural Sciences, Dalton State College
1
Patra, T.; Manna, S.; Maiti, D. Angew. Chem. Int. Ed. 2011,
Notes
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.
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complexes that require hydrogen per-
The authors declare no competing financial interest.
oxide and excess base to perform stoichiometric deformylation, see: (a)
Seo, M. S.; Kim, J. Y.; Annaraj, J.; Kim, Y.; Lee, Y.-M.; Kim, S.-J.;
Kim, J.; Nam, W. Angew. Chem., Int. Ed. 2007, 46 (3), 377-380; (b) Jo,
Y.; Annaraj, J.; Seo, M. S.; Lee, Y.-M.; Kim, S. Y.; Cho, J.; Nam, W.
J. Inorg. Biochem. 2008, 102 (12), 2155-2159; (c) Cho, J.; Sarangi, R.;
Nam, W. Acc. Chem. Res. 2012, 45 (8), 1321-1330; (d) Cho, J.; Kang,
H. Y.; Liu, L. V.; Sarangi, R.; Solomon, E. I.; Nam, W. Chem. Sci.
2013, 4 (4), 1502-1508; (e) Shokri, A.; Que, L. J. Am. Chem. Soc. 2015,
ACKNOWLEDGMENT
We thank NSF for support (CHE-1205646). J.F.B. thanks the
DOE (DE-FG02-10ER16204). K.M.L thanks Cornell Uni-
versity for startup funding and NSF (CHE-1454455). A.R.C.
thanks the NSF (DGE-0718123). R.C.W. thanks the NIH-
NIGMS (T32GM008500). Computational (CHE-0840494)
and EPR facilities (CHE-0741901) at UW-Madison are sup-
ported by NSF. We thank Dr. Elizabeth Blaesi for insightful
discussions. This work is based on research conducted at the
Cornell High Energy Synchrotron Source (CHESS), sup-
ported by NSF and NIH/NIGMS under NSF award DMR-
137 (24), 7686-7691.
II
9.
For a Cu -superoxide complex that is capable of stoichio-
2
metric deformylation but requires superoxide, not O , see: (a)
Donoghue, P. J.; Gupta, A. K.; Boyce, D. W.; Cramer, C. J.; Tolman,
W. B. J. Am. Chem. Soc. 2010, 132 (45), 15869-15871; (b) Pirovano,
P.; Magherusan, A. M.; McGlynn, C.; Ure, A.; Lynes, A.; McDonald,
A. R. Angew. Chem. Int. Ed. 2014, 53 (23), 5946-5950; (c) Ure, A. D.;
McDonald, A. R. Synlett 2015, 26 (15), 2060-2066.
1
332208.
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0.
Classification of reactive metal-oxygen species as electro-
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