Journal of Organic Chemistry p. 3042 - 3050 (2016)
Update date:2022-08-25
Topics:
Chen, Fei
Yang, Xiu-Long
Wu, Zhi-Wei
Han, Bing
A novel, metal-free, and regioselective approach for the synthesis of isoxazoline/cyclic nitrone-featured methylenes has been developed by the reaction of readily accessible β,γ- and γ,δ-unsaturated ketoximes with TEMPO via tandem iminoxyl radical-promoted cyclization/TEMPO-mediated Cope-like elimination, respectively. This protocol utilizes commercially available TEMPO as the iminoxyl radical initiator as well as the β-hydrogen acceptor in the Cope-like elimination.
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Doi:10.1039/c6nj00728g
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