Synthetic Communications p. 2491 - 2498 (1998)
Update date:2022-08-11
Topics:
Stanetty, Peter
Kremslehner, Manfred
The reaction of various organometallics with 2-nitro-1- phenylsulfonylpropene 2a and 2-nitro-1-phenylthiopropene 2b was investigated. While in the case of lithium and magnesium organyls the addition products 4 were formed, transmetallation with CuCN led exclusively to (E)-nitro olefins 3.
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