Journal of the American Chemical Society p. 2600 - 2607 (1988)
Update date:2022-08-11
Topics:
Chiang, Y.
Kresge, A.J.
Krogh, E.T.
The enol isomer of diphenylacetaldehyde was generated in aqueous solution from its potassium salt, formed by treating the aldehyde, with potassium hydride, and rates of ketonization of this enol were measured at 25 deg C in perchloric acid and sodium hydroxide solutions and acetic acid and bicarbonate ion buffers.These data, coupled with rates of enolization of the aldehyde measured at 25 deg C in acetic acid buffer and sodium hydroxide solutions, lead to duplicate independent determinations of the keto-enol equilibrium constant,
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