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Name	GLYCERYL TRIBENZOATE	EINECS	N/A
CAS No.	614-33-5	Density	1.243g/cm³
PSA	78.90000	LogP	3.92600
Solubility	N/A	Melting Point	68-72 °C(lit.)
Formula	C24H20 O6	Boiling Point	548.9°C at 760 mmHg
Molecular Weight	404.419	Flash Point	238.1°C
Transport Information	N/A	Appearance	N/A
Safety	Mildly toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.	Risk Codes	N/A
Molecular Structure		Hazard Symbols	N/A
Synonyms	1,2,3-Propanetriol,tribenzoate (9CI); Glycerol, tribenzoate (6CI,7CI,8CI); Benzoflex S 404;Glyceryl tribenzoate; NSC 2230; Tribenzoin; Uniplex 260	Article Data	23

GLYCERYL TRIBENZOATE Synthetic route

: 56-81-5
glycerol

: 65-85-0
benzoic acid

: 614-33-5
glyceryl tribenzoate

Conditions

Conditions	Yield
With calcium hydroxide In 5,5-dimethyl-1,3-cyclohexadiene; decane at 220℃; for 1h; Solvent; Reagent/catalyst; Reflux; Large scale;	99.2%
With H2SO4/TiO2-La2O3-solid acid catalyst at 185 - 195℃; for 12h;	88.6%
at 200℃; anschl. auf 270grad;
at 200℃; dann auf 270grad im Druckrohr erhitzen;
With silicate-catalyst at 200 - 220℃; unter Entfernen des entstehenden Wassers;

: 98-88-4
benzoyl chloride

: 56-81-5
glycerol

: 614-33-5
glyceryl tribenzoate

Conditions

Conditions	Yield
With dmap; triethylamine In dichloromethane at 20℃; for 16h; Cooling with ice;	70%

: 110-86-1
pyridine

: 98-88-4
benzoyl chloride

: 56-81-5
glycerol

: 614-33-5
glyceryl tribenzoate

: 98-88-4
benzoyl chloride

: furan-2,3,5(4H)-trione pyridine (1:1)

: 100-79-8
(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol

: 614-33-5
glyceryl tribenzoate

: 96-11-7
1,2,3-tribromopropane

: 582-25-2
Potassium benzoate

: 614-33-5
glyceryl tribenzoate

Conditions

Conditions	Yield
at 200℃;

: 119-53-9
2-hydroxy-2-phenylacetophenone

: 65-85-0
benzoic acid

: 614-33-5
glyceryl tribenzoate

Conditions

Conditions	Yield
at 250℃;

: 3376-59-8
2,3-dihydroxypropyl benzoate

: 98-88-4
benzoyl chloride

: furan-2,3,5(4H)-trione pyridine (1:1)

: 614-33-5
glyceryl tribenzoate

: 98-88-4
benzoyl chloride

: furan-2,3,5(4H)-trione pyridine (1:1)

: 56-81-5
glycerol

: 614-33-5
glyceryl tribenzoate

: 93-97-0
benzoic acid anhydride

: 56-81-5
glycerol

: 614-33-5
glyceryl tribenzoate

Conditions

Conditions	Yield
at 200℃;
at 200℃;

: 96-11-7
1,2,3-tribromopropane

: 65-85-0
benzoic acid

: 614-33-5
glyceryl tribenzoate

Conditions

Conditions	Yield
at 200℃; bei der Einwirkung auf Kaliumbenzoat;

GLYCERYL TRIBENZOATE Chemical Properties

Glycerol tribenzoate(614-33-5)'s molecular formula is C₂₄H₂₀O₆ and its formula weight is 404.41.
Glycerol tribenzoate(614-33-5) has a melting point of 68-72 °C(lit.).
The molecular structure of glycerol tribenzoate(614-33-5):

GLYCERYL TRIBENZOATE Toxicity Data With Reference

orl-rat LD50:11,700 mg/kg

NPIRI* Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. 2 (1975),59.

GLYCERYL TRIBENZOATE Consensus Reports

Reported in EPA TSCA Inventory.

GLYCERYL TRIBENZOATE Safety Profile

Mildly toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.

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