- Glycine
- Glycine 1-methylethyl ester
- Glycine ethyl ester hydrochloride
- Glycine hydrochloride
- Glycine isopropyl ester hydrochloride
- Glycine lauryl ester hydrochloride
- Glycine Methyl ester Hydrochloride
- GLYCINE NITROGEN MUSTARD
- Glycine sodium salt
- Glycine sodium salt carbonate
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Cas Database |
| Name |
Glycine ethyl ester hydrochloride |
EINECS | 210-787-4 |
| CAS No. | 623-33-6 | Density | 1 g/cm3 |
| PSA | 52.32000 | LogP | 1.01050 |
| Solubility | >1000 g/L (20 °C) in water | Melting Point |
145-146 °C(lit.) |
| Formula | C4H10ClNO2 | Boiling Point | 109.5 °C at 760 mmHg |
| Molecular Weight | 139.582 | Flash Point | N/A |
| Transport Information | N/A | Appearance | Crystalline |
| Safety | 26-39-24/25 | Risk Codes | 41 |
| Molecular Structure |
|
Hazard Symbols |
 Xi
|
| Synonyms |
ethoxycarbonylmethylazanium;Glycine ethyl ester;Ethyl glycinate hydrochloride;Glycine hydrochloride ethyl ester;Ethyl aminoacetate hydrochloride;Ethyl glycinate;Glycine Ethylester Hydrochoride;H-Gly-OEt·HCl;Glycine Ethyl Ester HCl; |
Article Data | 55 |
Glycine ethyl ester hydrochloride Synthetic route
- 77385-90-1
N,N-dibenzylglycine ethyl ester
- 623-33-6
glycine ethyl ester hydrochloride
| Conditions | Yield |
|---|---|
| With 1,1,2-trichloroethane; 10% palladium on activated carbon; hydrogen In methanol under 760.051 Torr; for 1h; chemoselective reaction; | 99% |
| Conditions | Yield |
|---|---|
| With thionyl chloride at 25 - 30℃; for 0.583333h; microwave irradiation; | 98% |
| With thionyl chloride Reflux; | 97% |
| With thionyl chloride at -10 - 20℃; for 2h; Heating / reflux; | 90.4% |
- 85231-98-7
C13H26NO7P
- 623-33-6
glycine ethyl ester hydrochloride
| Conditions | Yield |
|---|---|
| With hydrogenchloride In benzene Ambient temperature; | 91% |
| Conditions | Yield |
|---|---|
| With thionyl chloride In ethanol at -10℃; for 2h; Heating / reflux; | 90.4% |
| With thionyl chloride In ethanol for 2h; | 90.4% |
| Conditions | Yield |
|---|---|
| With thionyl chloride at -20℃; for 2h; Reflux; Inert atmosphere; | 90% |
| Conditions | Yield |
|---|---|
| at -5 - 60℃; for 4h; | 85% |
| Conditions | Yield |
|---|---|
| With triphenylphosphine In tetrahydrofuran; water for 12h; Ambient temperature; | 83% |
- 14011-27-9
ethyl chloronitroacetate
- 623-33-6
glycine ethyl ester hydrochloride
| Conditions | Yield |
|---|---|
| With hydrogen; palladium on activated charcoal In ethanol at 35 - 40℃; | 65.3% |
| Conditions | Yield |
|---|---|
| With ammonium formate; palladium on activated charcoal In methanol for 0.333333h; Ambient temperature; | 64% |
- 64-17-5
ethanol
- 80478-56-4
ethyl N-(2-diethoxyacetyl)glycinate
A
- 623-33-6
glycine ethyl ester hydrochloride
B
- 6065-82-3
Ethyl diethoxyacetate
| Conditions | Yield |
|---|---|
| With hydrogenchloride for 3h; Heating; | A 35% B 38% |
| With hydrogenchloride for 3h; Product distribution; Heating; | A 35% B 38% |
Glycine ethyl ester hydrochloride Chemical Properties
Molecular Structure of Glycine ethyl ester hydrochloride (CAS NO.623-33-6):
.png)
IUPAC Name: ethyl 2-aminoacetate hydrochloride
Name : Glycine ethyl ester hydrochloride
Molecular Formula : C4H9NO2.HCl; C4H10ClNO2
Molecular Weight : 139.58
CAS Registry Number : 623-33-6
EINECS : 210-787-4
BRN: 3594034
H bond acceptors: 3
H bond donors: 2
Freely Rotating Bonds: 4
Polar Surface Area: 26.3 Å2
Storage temp: Store at RT
Melting point: 145-148 oC
Water solubility: >1000 g/L (20 oC)
Solubility: >1000 g/L (20 °C)
Sensitive: Hygroscopic
Enthalpy of Vaporization: 34.82 kJ/mol
Boiling Point: 109.5 °C at 760 mmHg
Vapour Pressure: 24.7 mmHg at 25°C
InChI
InChI=1/C4H9NO2.ClH/c1-2-7-4(6)3-5;/h2-3,5H2,1H3;1H
Smiles
C(OCC)(C[NH3+])=O.[ClH-]
Product Categories: Food and Feed Additive; Amino Acid Derivatives; Amino Acids; Glycine [Gly, G]; Amino Acids and Derivatives; Amino Acid Ethyl Esters; Amino Acids (C-Protected); Biochemistry; Amino hydrochloride
Glycine ethyl ester hydrochloride Toxicity Data With Reference
| 1. | ipr-mus LD50:750 mg/kg | NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) AD277-689 . |
Glycine ethyl ester hydrochloride Consensus Reports
Reported in EPA TSCA Inventory.
Glycine ethyl ester hydrochloride Safety Profile
Moderately toxic by intraperitoneal route. When heated to decomposition it emits toxic vapors of NOx, HCl, and Cl−.
Hazard Codes: 
Xi
Risk Statements: 41
R41:Risk of serious damage to the eyes.
Safety Statements: 26-39-24/25
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S39:Wear eye / face protection.
S24/25:Avoid contact with skin and eyes.
WGK Germany: 3
RTECS: MC0525000
HS Code: 29224995
Glycine ethyl ester hydrochloride Specification
Glycine ethyl ester hydrochloride , with CAS number of 623-33-6, can be called Glycineethylesterhydrochlor ; Glycocollethylesterhydrochloride ; usafdo-10 ; H-gly-oet HCl ; Glycine ethyl ester ; Glycine ethyl ester HCl ; Glycine ethyl ester hydrochloride ; Glycine-oet HCl .
Glycine ethyl ester hydrochloride (CAS NO.623-33-6) is pesticide and pharmaceutical intermediates, also used in biochemical research. It has been prepared by the action of absolute alcohol and hydrogen chloride on glycine;from glycyl chloride and alcohol;by the action of ammonia or hexamethylenetetramine on chloroacetic acid, and subsequent hydrolysis with alcoholic hydrochloric acid; by the action of hydrogen chloride and alcohol onmethyleneaminoacetonitrile;and by the reduction of ethyl cyanoformate or the corresponding imido ester hydrochloride.
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