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Cas Database |
| Name |
Hexachloropropene |
EINECS | 217-560-9 |
| CAS No. | 1888-71-7 | Density | 1.765 g/mL at 25 °C(lit.) |
| PSA | 0.00000 | LogP | 4.24210 |
| Solubility |
Stability
Toxicology
|
Melting Point |
-73°C |
| Formula | C3Cl6 | Boiling Point |
209-210 °C(lit.) |
| Molecular Weight | 248.751 | Flash Point | 209-210°C |
| Transport Information | N/A | Appearance | colourless liquid |
| Safety | A poison by inhalation and intraperitoneal routes. A powerful irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl−. See also CHLORINATED HYDROCARBONS, ALIPHATIC. | Risk Codes | R23; R36/37/38 |
| Molecular Structure |
|
Hazard Symbols |
 T
|
| Synonyms |
Propene,hexachloro- (6CI,7CI,8CI); 1,1,1,2,3,3-Hexachloropropene; Hexachloro-1-propene;Hexachloropropene; Hexachloropropylene; NSC 7297; Perchloropropene;Perchloropropylene |
Article Data | 35 |
Hexachloropropene Synthetic route
| Conditions | Yield |
|---|---|
| With methyl diethylphosphinate at 180℃; for 14.5h; | 56% |
| With potassium hydroxide | |
| at 250 - 420℃; |
- 131367-96-9
trichloro(heptachloropropyl)silane
- 1888-71-7
perchloropropene
| Conditions | Yield |
|---|---|
| With aluminium trichloride at 160 - 180℃; | 52% |
- 87651-34-1
pentachloro-2-(trimethylsiloxy)propene
A
- 75-77-4
chloro-trimethyl-silane
B
- 1768-31-6
pentachloroacetone
C
- 1888-71-7
perchloropropene
| Conditions | Yield |
|---|---|
| With phosphorus pentachloride at 150℃; for 15h; Yields of byproduct given; | A 52% B n/a C n/a |
| With phosphorus pentachloride at 150℃; for 15h; Yield given. Title compound not separated from byproducts; | A 52% B n/a C n/a |
| Conditions | Yield |
|---|---|
| With hydrogen |
| Conditions | Yield |
|---|---|
| at 350℃; |
| Conditions | Yield |
|---|---|
| With aluminium trichloride |
- 25290-40-8
heptachloro-butyraldehyde
- 1888-71-7
perchloropropene
| Conditions | Yield |
|---|---|
| With sodium ethanolate |
| Conditions | Yield |
|---|---|
| With chlorine at 200℃; Irradiation; |
| Conditions | Yield |
|---|---|
| With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride In chloroform |
- 18608-30-5
perchloroallene
- 1888-71-7
perchloropropene
| Conditions | Yield |
|---|---|
| With chlorine In dichloromethane |
Hexachloropropene Chemical Properties
IUPAC Name: 1,1,2,3,3,3-Hexachloroprop-1-ene
Molecular Formula: C3Cl6
Molecular Weight: 248.73g/mol
EINECS: 217-560-9
Transport information: UN 3382 6.1/PG 1
Properties colourless liquid
Density: 1.781 g/cm3
Flash Point: 69.9 °C
Boiling Point: 209.5 °C at 760 mmHg
Freely Rotating Bonds: 0
Polar Surface Area: 0 Å2
Index of Refraction: 1.554
Molar Refractivity: 44.75 cm3
Molar Volume: 139.6 cm3
Polarizability: 17.74 ×10-24 cm3
Surface Tension: 42.6 dyne/cm
Enthalpy of Vaporization: 42.76 kJ/mol
Vapour Pressure: 0.292 mmHg at 25°C
Stability: stable,incompatible with strong oxidizing agents.
Solubility: insoluble in water
The Cas Register Number of Hexachloropropene is 1888-71-7.The chemical synonyms of Hexachloropropene (CAS NO.1888-71-7) are 1,1,1,2,3,3-Hexachloropropene ; 1,1,2,3,3,3-Hexachloro-1-propen ; 1,1,2,3,3,3-Hexachloro-1-propene ; 1,1,2,3,3-Hexachloro-1-propene ; 1-Propene, hexachloro- ; 1-Propene,1,1,2,3,3,3-hexachloro ; 1-Propene,1,1,2,3,3,3-hexachloro- ; Hexachloro-1-propene .The molecular structure of Hexachloropropene (CAS NO.1888-71-7) is.bmp)
.
Hexachloropropene Uses
Hexachloropropene (CAS NO.1888-71-7) is used as plasticizer and hydraulic fluid .And it also is used in organic synthesis.
Hexachloropropene Production
Its raw materials are Potassium ethylate and 1,1,1,2,2,3,3-Heptachloropropane .
Hexachloropropene Toxicity Data With Reference
| 1. | mmo-sat 15 µmol/L | MUREAV Mutation Research. 170 (1986),1. | ||
| 2. | ihl-rat LC50:425 ppm/30M | XEURAQ U.S. Atomic Energy Commission, University of Rochester, Research and Development Reports. (Rochester, NY) MDDC-1715 . | ||
| 3. | ipr-rat LD50:400 mg/kg | XEURAQ U.S. Atomic Energy Commission, University of Rochester, Research and Development Reports. (Rochester, NY) MDDC-1715 . | ||
| 4. | ihl-mus LCLo:300 ppm/30M | XEURAQ U.S. Atomic Energy Commission, University of Rochester, Research and Development Reports. (Rochester, NY) MDDC-1715 . | ||
| 5. | ipr-mus LDLo:64 mg/kg | CBCCT* “Summary Tables of Biological Tests“ National Research Council Chemical-Biological Coordination Center. 1 (1949),46. | ||
| 6. | ihl-rbt LCLo:85 ppm/30M | XEURAQ U.S. Atomic Energy Commission, University of Rochester, Research and Development Reports. (Rochester, NY) MDDC-1715 . |
Hexachloropropene Consensus Reports
Reported in EPA TSCA Inventory.
Hexachloropropene Safety Profile
A poison by inhalation and intraperitoneal routes. A powerful irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl−. See also CHLORINATED HYDROCARBONS, ALIPHATIC.
Hazard Codes: 
T
Risk Statements: 23-36/37/38
R23: Toxic by inhalation.
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36/37/39-45
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
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