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Cas Database |
| Name |
Hexamethylolmelamine |
EINECS | N/A |
| CAS No. | 531-18-0 | Density | 1.821g/cm3 |
| PSA | 169.77000 | LogP | -4.01040 |
| Solubility | N/A | Melting Point |
150℃ |
| Formula | C9H18 N6 O6 | Boiling Point | 669°Cat760mmHg |
| Molecular Weight | 306.279 | Flash Point | 358.4°C |
| Transport Information | N/A | Appearance | N/A |
| Safety | A poison by intravenous route. A skin and eye irritant. When heated to decomposition it emits toxic fumes of NOx. | Risk Codes | N/A |
| Molecular Structure |
|
Hazard Symbols | N/A |
| Synonyms |
Methanol,(1,3,5-triazine-2,4,6-triyltrinitrilo)hexakis- (9CI); Methanol, (s-triazine-2,4,6-triyltrinitrilo)hexa-(6CI,7CI,8CI); 1,3,5-Triazine-2,4,6-triamine, hexakis(hydroxymethyl)-;2,4,6-Tris[di(hydroxymethyl)amino]-1,3,5-triazine; Cilag 61;Hexa(hydroxymethyl)melamine; Hexakis(hydroxymethyl)melamine;Hexamethylolmelamine; NSC 118741; Resloom M 75 |
Article Data | 17 |
Hexamethylolmelamine Synthetic route
| Conditions | Yield |
|---|---|
| In water pH=7.5; Heating; | 86% |
| With hydrogenchloride | |
| With sodium hydroxide |
| Conditions | Yield |
|---|---|
| With dmap; dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 24h; Inert atmosphere; | 95% |
- 531-18-0
hexa(hydroxymethyl)melamine
- 35948-25-5
9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide
- 66499-32-9
N,N,N',N',N'',N''-Hexakis-(10-oxo-10H-9-oxa-10λ5-phospha-phenanthren-10-ylmethyl)-[1,3,5]triazine-2,4,6-triamine
| Conditions | Yield |
|---|---|
| With benzenesulfonic acid at 165 - 240℃; | 89% |
- 67-56-1
methanol
- 531-18-0
hexa(hydroxymethyl)melamine
- 3089-11-0
hexakis-N-methoxymethyl-[1,3,5]triazine-2,4,6-triamine
| Conditions | Yield |
|---|---|
| With hydrogenchloride | |
| With nitric acid In water at 45 - 55℃; for 1.5h; pH=1.5 - 3.8; Product distribution / selectivity; | |
| With hydrogenchloride In water at 35℃; for 2h; pH=2.5; pH-value; Temperature; |
- 531-18-0
hexa(hydroxymethyl)melamine
- 50693-84-0
hexakis-N-chloromethyl-[1,3,5]triazine-2,4,6-triamine
| Conditions | Yield |
|---|---|
| With phosphorus trichloride In N,N-dimethyl-formamide at 0℃; |
- 531-18-0
hexa(hydroxymethyl)melamine
- 75-57-0
tetramethlyammonium chloride
- 106-89-8
epichlorohydrin
- 71-36-3
butan-1-ol
| Conditions | Yield |
|---|---|
| With sodium hydroxide In water | |
| With sodium hydroxide In water |
- 531-18-0
hexa(hydroxymethyl)melamine
| Conditions | Yield |
|---|---|
| With ammonia In methanol at 50 - 60℃; under 1140.08 Torr; for 2h; Inert atmosphere; Autoclave; |
| Conditions | Yield |
|---|---|
| In ethanol at 60 - 80℃; for 3h; |
| Conditions | Yield |
|---|---|
| In ethanol at 30 - 60℃; for 3h; |
Hexamethylolmelamine Chemical Properties
IUPAC Name: [[4,6-Bis[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol
The MF of 1,3,5-Triazine-2,4,6-triyltrinitrilohexamethanol (CAS NO.531-18-0) is C9H18N6O6.
The MW of 1,3,5-Triazine-2,4,6-triyltrinitrilohexamethanol (CAS NO.531-18-0) is 306.27582.
Synonyms of 1,3,5-Triazine-2,4,6-triyltrinitrilohexamethanol (CAS NO.531-18-0): Hexamethylolmelamine ; (1,3,5-Triazine-2,4,6-triyltrinitrilo)hexakismethanol ; Methanol, 1,1',1'',1''',1'''',1'''''-(1,3,5-triazine-2,4,6-triyltrinitrilo)hexakis- ; (s-Triazine-2,4,6-triyltrinitrilo)hexamethanol ; 1,3,5-Triazine-2,4,6-triamine, hexakis(hydroxymethyl)- ; 1,3,5-Triazine-2,4,6-triyltrinitrilohexamethanol
Index of Refraction: 1.812
EINECS: 208-503-9
Density: 1.821 g/ml
Flash Point: 358.4 °C
Boiling Point: 669 °C
Hexamethylolmelamine Toxicity Data With Reference
| 1. | skn-rbt 20 mg/24H MOD | 85JCAE Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,876. | ||
| 2. | eye-rbt 100 mg/24H MOD | 28ZPAK Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,154. | ||
| 3. | ivn-mus LD50:180 mg/kg | CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#04006 . |
Hexamethylolmelamine Consensus Reports
Reported in EPA TSCA Inventory.
Hexamethylolmelamine Safety Profile
A poison by intravenous route. A skin and eye irritant. When heated to decomposition it emits toxic fumes of NOx.
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