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Lithium aluminium hydride

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Lithium aluminium hydride

EINECS 240-877-9
CAS No. 16853-85-3 Density 0.917
PSA 0.00000 LogP 0.45000
Solubility reacts with water Melting Point 125 °C (dec.)(lit.)
Formula AlH4.Li Boiling Point 0 °C
Molecular Weight 37.9543 Flash Point 99 °F
Transport Information UN 3399 4.3/PG 1 Appearance white crystalline powder
Safety 43-7/8-6A-45-43B-36/37/39-33-26-16-24/25-27-29 Risk Codes 15-34-14/15-11-36/37-19-40-10-67-66-22-12
Molecular Structure Molecular Structure of 16853-85-3 (Lithium aluminium hydride) Hazard Symbols FlammableF,CorrosiveC
Synonyms

Aluminate(1-),tetrahydro-, lithium (8CI);Aluminate(1-), tetrahydro-, lithium, (T-4)- (9CI);Aluminum lithium hydride (LiAlH4) (6CI);Aluminum lithium tetrahydride;Lithiumalanate;Lithium aluminum hydride (LiAlH4);Lithiumaluminum tetrahydride;Lithium tetrahydridoaluminate;Lithiumtetrahydroaluminate;Lithium tetrahydroaluminate (AlLiH4);Lithiumtetrahydroaluminate(1-);

Article Data 15

Lithium aluminium hydride Chemical Properties

Product Name: Lithium aluminium hydride (CAS NO.16853-85-3)

Molecular Formula: LiAlH4
Molecular Weight: 37.95g/mol
Mol File: 16853-85-3.mol
EINECS: 240-877-9
Appearance: Clear colourless liquid
Melting Point: 125 °C (dec.)(lit.)
Storage Temperature: 2-8°C
Water Solubility: Reacts
Sensitive: Air & Moisture Sensitive
Stability: Stable. Reacts violently with water, liberating hydrogen. Incompatible with strong oxidizing agents, alcohols, acids.
Product Categories: Inorganics; Al (Alminum) Compounds; Classes of Metal Compounds; Li (Lithium) Compounds; Reduction; Synthetic Organic Chemistry; Typical Metal Compounds; Aluminum Hydrides; Synthetic Reagents

Lithium aluminium hydride Uses

Used for determination reagents of carbonyl, reducing agents, but also for preparation of the hydride, silane, boron, etc.

Lithium aluminium hydride Consensus Reports

Reported in EPA TSCA Inventory.

Lithium aluminium hydride Safety Profile

Safety Information of  Lithium aluminium hydride (CAS NO.16853-85-3):
Hazard Codes: FFlammable,CCorrosive,XiIrritant,XnHarmful,F+Highly
Risk Statements:  15-34-14/15-11-36/37-19-40-10-67-66-22-12    
R15:Contact with water liberates extremely flammable gases. 
R34:Causes burns.
R14 :Reacts violently with water. 
R11:Highly flammable. 
R36/37:Irritating to eyes and respiratory system. 
R19:May form explosive peroxides. 
R40:Limited evidence of a carcinogenic effect. 
R10:Flammable. 
R67:Vapours may cause drowsiness and dizziness. 
R66:Repeated exposure may cause skin dryness or cracking. 
R22:Harmful if swallowed. 
R12:Extremely flammable.
Safety Statements: 43-7/8-6A-45-43B-36/37/39-33-26-16-24/25-27-29 
S43:In case of fire use ... (there follows the type of fire-fighting equipment to be used.) 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S43:In case of fire use ... (there follows the type of fire-fighting equipment to be used.) 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S33:Take precautionary measures against static discharges. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S16:Keep away from sources of ignition. 
S24/25:Avoid contact with skin and eyes. 
S27:Take off immediately all contaminated clothing. 
S29:Do not empty into drains.
RIDADR: UN 3399 4.3/PG 1
WGK Germany: 2
RTECS: BD0100000
F: 10-21
TSCA: Yes
HazardClass: 4.3
PackingGroup: I

Lithium aluminium hydride Standards and Recommendations

ACGIH TLV: TWA 2 mg(Al)/m3
DOT Classification:  4.3; Label: Dangerous When Wet (UN 1410); DOT Class: 4.3; Label: Dangerous When Wet, Flammable Liquid (UN 1411)

Lithium aluminium hydride Specification

 Lithium aluminium hydride , its CAS NO. is 16853-85-3, the synonyms are Aluminate(1-), tetrahydro-, lithium ; Aluminate(1-), tetrahydro-, lithium, (T-4)- ; Aluminum lithium hydride ; Lithium alanate ; Lithium aluminohydride ; Lithium aluminum hydride, ethereal ;  Lithium aluminum tetrahydride ; Lithium tetrahydroaluminate .

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