Welcome to LookChem.com Sign In|Join Free
  • or
Home > Products >  > 

Manganese(II) acetate tetrahydrate

Related Products

Hot Products

Basic Information Post buying leads Suppliers
Name

Manganese(II) acetate tetrahydrate

EINECS 211-334-3
CAS No. 6156-78-1 Density 1.589 g/mL at 25 °C(lit.)
PSA 89.52000 LogP -0.22960
Solubility Soluble in water, methanol, ethanol, and acetic acid. Melting Point >300 °C(lit.)
Formula C4H6MnO4.4(H2O) Boiling Point 117.1 °C at 760 mmHg
Molecular Weight 245.088 Flash Point 40 °C
Transport Information N/A Appearance pale pink crystal
Safety 26-36 Risk Codes 36/37/38
Molecular Structure Molecular Structure of 6156-78-1 (MANGANESE(II) ACETATE TETRAHYDRATE) Hazard Symbols IrritantXi
Synonyms

Manganeseacetate tetrahydrate;Manganese diacetate tetrahydrate;Manganese(2+) acetatetetrahydrate;Manganous acetatetetrahydrate;Manganese(II) acetate tetrahydrate;

 

Manganese(II) acetate tetrahydrate Synthetic route

75-07-0

acetaldehyde

64-19-7

acetic acid

6156-78-1

manganese (II) acetate tetrahydrate

Conditions
ConditionsYield
With manganese(IV) oxide; alkali cetate at 80℃;
With manganese(IV) oxide; alkaline earth acetate at 80℃;

C6H10(NCHC6H2C(CH3)3OHC15H10O(C(CH3)3)2)2(C6H4COOH)2

6156-78-1

manganese (II) acetate tetrahydrate

7647-14-5

sodium chloride

MnCl(C6H10(NCHC6H2C(CH3)3OC15H10O(C(CH3)3)2)2(C6H4COOH)2)

Conditions
ConditionsYield
In ethanol xanthene-compound was added to Mn(CH3CO2)2*4H2O in abs. ethanol, the soln. was refluxed in air for 2 h, cooled, aq. satd. NaCl was added, the mixt. was stirred for 10 min; extd. with CH2Cl2, the organic layer was washed with water, dried over MgSO4, the solid was rotary evapd.; elem. anal.;100%

5-[2-chloro-6-[(18-crown-6)methyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin

6156-78-1

manganese (II) acetate tetrahydrate

184765-61-5

Mn[5-[2-chloro-6-[(18-crown-6)methyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin](1+)

Conditions
ConditionsYield
In N,N-dimethyl-formamide stirring under reflux (4 h); solvent evapn. (vac.), dissolving in CH2Cl2, washing (water), chromy. (silica gel, CHCl3/EtOH), dissolving in CH2Cl2, stirring with NaCl soln., org. phase drying (MgSO4), solvent evapn.;100%

5-[2-chloro-6-[9-(18-crown-6)nonyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin

6156-78-1

manganese (II) acetate tetrahydrate

184765-68-2

Mn[5-[2-chloro-6-[9-(18-crown-6)nonyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin](1+)

Conditions
ConditionsYield
In N,N-dimethyl-formamide stirring under reflux (4 h); solvent evapn. (vac.), dissolving in CH2Cl2, washing (water), chromy. (silica gel, CHCl3/EtOH), dissolving in CH2Cl2, stirring with NaCl soln., org. phase drying (MgSO4), solvent evapn.;100%

5-[2,6-dichloro-3-[9-(18-crown-6)nonyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin

6156-78-1

manganese (II) acetate tetrahydrate

184765-75-1

Mn[5-[2,6-dichloro-3-[9-(18-crown-6)nonyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin](1+)

Conditions
ConditionsYield
In N,N-dimethyl-formamide stirring under reflux (4 h); solvent evapn. (vac.), dissolving in CH2Cl2, washing (water), chromy. (silica gel, CHCl3/EtOH), dissolving in CH2Cl2, stirring with NaCl soln., org. phase drying (MgSO4), solvent evapn.;100%

H2[C75H64Cl8N4O8]

6156-78-1

manganese (II) acetate tetrahydrate

184765-80-8

Mn[C75H64Cl8N4O8](1+)

Conditions
ConditionsYield
In N,N-dimethyl-formamide stirring under reflux (4 h); solvent evapn. (vac.), dissolving in CH2Cl2, washing (water), chromy. (silica gel, CHCl3/EtOH), dissolving in CH2Cl2, stirring with NaCl soln., org. phase drying (MgSO4), solvent evapn.;100%

K4[Re6Se8(CN)6]·3.5H2O

6156-78-1

manganese (II) acetate tetrahydrate

68-12-2, 33513-42-7

N,N-dimethyl-formamide

catena-(octakis(μ3-selenido)-hexakis(μ2-cyano)-hexarhenium(III)-aqua-bis(dimethylformamido)manganese(II))bis(dimethylformamide)

Conditions
ConditionsYield
In water; N,N-dimethyl-formamide soln. of K4(Re6Se8(CN)6)*3.5H2O (0.08 mmol) in H2O/DMF added to soln. ofMn(CH3COO)2*4H2O (0.18 mmol) in H2O/DMF under stirring, mixt. refluxed for 1 h, cooled; ppt. filtered off, washed twice with H2O/DMF and CH3CN, air-dried; elem.anal.;100%

4K(1+)*[Re6S8(CN)6](4-)=K4[Re6S8(CN)6]

6156-78-1

manganese (II) acetate tetrahydrate

68-12-2, 33513-42-7

N,N-dimethyl-formamide

catena-(octakis(μ3-sulfido)-hexakis(μ2-cyano)-hexarhenium(III)-aqua-bis(dimethylformamido)manganese(II))bis(dimethylformamide)

Conditions
ConditionsYield
In water mixt. of H2O/DMF (75/1) added dropwise to aq. soln. of K4(Re6S8(CN)6) (0.029 mmol) and Mn(CH3COO)2*4H2O (0.068 mmol) under stirring; soln. concd., stored in air for a week, crystals filtered off, washed twice (CH3CN), air-dried; elem. anal.;100%

4Cs(1+)*Re6Te8(CN)6(4-) = Cs4[Re6Te8(CN)6]

6156-78-1

manganese (II) acetate tetrahydrate

68-12-2, 33513-42-7

N,N-dimethyl-formamide

catena-(octakis(μ3-tellurido)-hexakis(μ2-cyano)-hexarhenium(III)-aqua-bis(dimethylformamido)manganese(II))bis(dimethylformamide)

Conditions
ConditionsYield
In water; N,N-dimethyl-formamide soln. of Cs4(Re6Te8(CN)6) (0.08 mmol) in H2O/DMF slowly added to soln. of Mn(CH3COO)2*4H2O (0.18 mmol) in H2O/DMF under stirring, mixt. refluxedfor 1 h, cooled; ppt. filtered off, washed with H2O/DMF and CH3CN, air-dried; elem. anal.;100%

K4[Re6Se8(CN)6]·3.5H2O

6156-78-1

manganese (II) acetate tetrahydrate

68-12-2, 33513-42-7

N,N-dimethyl-formamide

catena-(octakis(μ3-selenido)-hexakis(μ2-cyano)-hexarhenium(III)-tris(dimethylformamido)manganese(II))

Conditions
ConditionsYield
In water; N,N-dimethyl-formamide soln. of K4(Re6Se8(CN)6)*3.5H2O in H2O/DMF added to soln. of Mn(CH3COO)2*4H2O in H2O/DMF with vigorous stirring, mixt. stirred for 2 h; ppt. filtered off, washed twice with H2O/DMF (1/1) and CH3CN, air-dried;elem. anal.;100%

Manganese(II) acetate tetrahydrate Consensus Reports

Manganese and its compounds are on the Community Right-To-Know List.

Manganese(II) acetate tetrahydrate Standards and Recommendations

OSHA PEL: CL 5 mg(Mn)/m3
ACGIH TLV: TWA 5 mg(Mn)/m3

Manganese(II) acetate tetrahydrate Specification

The Manganese(II) acetate tetrahydrate is an organic compound with the formula C4H6MnO4.4(H2O). The IUPAC name of this chemical is manganese(2+) diacetate tetrahydrate. With the CAS registry number 6156-78-1, it is also named as acetic acid, manganese(2+) salt, hydrate (2:1:2). Besides, it is a pale pink crystal, which should be stored in a dark cool and dry place. It is the raw material of polyester resin, xylene oxidation catalyst, which is used as oxidation catalysts and paint driers.

Physical properties about Manganese(II) acetate tetrahydrate are: (1)ACD/LogP: -0.285; (2)ACD/LogD (pH 5.5): -1.07; (3)ACD/LogD (pH 7.4): -2.86; (4)ACD/BCF (pH 5.5): 1.00; (5)ACD/BCF (pH 7.4): 1.00; (6)ACD/KOC (pH 5.5): 2.73; (7)ACD/KOC (pH 7.4): 1.00; (8)#H bond acceptors: 2; (9)#H bond donors: 1; (10)Flash Point: 40 °C; (11)Enthalpy of Vaporization: 23.7 kJ/mol; (12)Boiling Point: 117.1 °C at 760 mmHg; (13)Vapour Pressure: 13.9 mmHg at 25°C

Preparation of Manganese(II) acetate tetrahydrate : this chemical can be prepared by Manganese and Acetic acid.

When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable suitable protective clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)InChI=1S/2C2H4O2.Mn.4H2O/c2*1-2(3)4;;;;;/h2*1H3,(H,3,4);;4*1H2/q;;+2;;;;/p-2;
(2)InChIKey=CESXSDZNZGSWSP-UHFFFAOYSA-L;
(3)SmilesC(C)(=O)[O-].C(=O)([O-])C.[Mn+2].O.O.O.O

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LD50 oral 3730mg/kg (3730mg/kg)   American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 6156-78-1