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Cas Database

Name	Manganese(II) phthalocyanine	EINECS	N/A
CAS No.	14325-24-7	Density	N/A
PSA	84.02000	LogP	1.46440
Solubility	Soluble in pyridine, chloronaphthalene, and conc. sulfuric acid. Insoluble in water.	Melting Point	>300 °C
Formula	C₃₂H₁₆MnN₈	Boiling Point	N/A
Molecular Weight	567.471	Flash Point	N/A
Transport Information	N/A	Appearance	N/A
Safety	22-24/25	Risk Codes	N/A
Molecular Structure		Hazard Symbols	N/A
Synonyms	Manganese,[29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, (SP-4-1)-;Manganese, [phthalocyaninato(2-)]-(6CI,7CI,8CI);29H,31H-Phthalocyanine, manganese complex;(Phthalocyaninato)manganese;KJB 006;Manganese phthalocyanine;Manganese(II)phthalocyanine;[Phthalocyaninato(2-)]manganese;	Article Data	19

Manganese(II) phthalocyanine Synthetic route

: 6156-78-1
manganese (II) acetate tetrahydrate

: 91-15-6
phthalonitrile

: 14325-24-7
manganese(II) phthalocyanin

Conditions

Conditions	Yield
In ethanol at 190℃; for 3h; Autoclave; High pressure; Green chemistry;	45%
In ethanol at 190℃; for 1h; Temperature; Solvent; Autoclave;	40%

: 85-44-9
phthalic anhydride

: manganese(II)

: 57-13-6
urea

: 14325-24-7
manganese(II) phthalocyanin

Conditions

Conditions	Yield
With (NH4)2Mo2O7 In neat (no solvent) other Radiation; mixt. of O-phthalic anhydride, urea, metal salt and (NH4)2Mo2O7 irradiated in microwave oven at 460W for 8 min. the at 800W for 8 min, cooling to room temp.; washed (H2O, acetone, MeOH, 6M HCl), reflux with acetone, MeOH and CHCl3resp. about 12 h; elem. anal.;	31%

: 7439-96-5
manganese

: hexaammonium heptamolybdate tetrahydrate

: 91-15-6
phthalonitrile

: 14325-24-7
manganese(II) phthalocyanin

Conditions

Conditions	Yield
With I2 In neat (no solvent) tube was loaded with ligand, Mn, I2 and (NH4)6Mo7O24*4H2O under N2, tube was immersed in a 300°C salt bath, after a few min mixt. was solidified, mixt. was left at 300°C for 6 h, cooled; powder was sublimed in a tube furnace in vac. over 2 d at 480°C, crude ppt. was resublimed in vac. at <=460°C (caution: unsublimed material is pyrophoric); elem. anal.;	21%

: 68027-09-8
oxovanadium phthalocyanine

: 14325-24-7
manganese(II) phthalocyanin

Conditions

Conditions	Yield
With imidazole In N,N-dimethyl acetamide soln. of complex in DMA was degassed, imidazole was added, 10 min; product was not isolated; analyzed by ESR or UV;

: manganese(II)

: 91-15-6
phthalonitrile

: 14325-24-7
manganese(II) phthalocyanin

Conditions

Conditions	Yield
In not given react. of phthalonitrile with Mn(2+); washing, sublimation;

: manganese(II) sulfate

: 91-15-6
phthalonitrile

: 14325-24-7
manganese(II) phthalocyanin

Conditions

Conditions	Yield
In methanol React. at 65-100°C, 9-11.5 kbar for 1.75-18 h in presence of hydroquinone.; Extg. with MeOH and acetone, sublimed in vac.;	2-50

: 63105-50-0
Mn(OH)-phthalocyanine

: 14325-24-7
manganese(II) phthalocyanin

Conditions

Conditions	Yield
In not given Irradiation (UV/VIS);

: 77648-32-9
(phthalocyaninato)bis(pyridine)manganese(II)

: 14325-24-7
manganese(II) phthalocyanin

Conditions

Conditions	Yield
In neat (no solvent) above 180°C;

: manganese phthalocyanine (1-)

: 14325-24-7
manganese(II) phthalocyanin

Conditions

Conditions	Yield
In tetrahydrofuran; N,N-dimethyl-formamide Irradiation (UV/VIS);

: manganese(II) sulfate

: 85-44-9
phthalic anhydride

: 14325-24-7
manganese(II) phthalocyanin

Conditions

Conditions	Yield
With ammonium heptamolybdate; urea Microwave irradiation;

Manganese(II) phthalocyanine Specification

The CAS register number of Manganese(II) phthalocyanine is 14325-24-7. It also can be called as Manganese, (29H,31H-phthalocyaninato(2-)-kappaN29,kappaN30,kappaN31,kappaN32)-, (SP-4-1)- and the systematic name about this chemical is 29H,31H-phthalocyanine, manganese(2+) salt (1:1). The molecular formula about this chemical is C₃₂H₁₆MnN₈and the molecular weight is 567.46. It belongs to the Organometallics. When you are using it, please avoid contact with skin and eyes and do not breathe dust. This chemical is a compound of manganese and phthalocyanine.

Physical properties about Manganese(II) phthalocyanine are: (1)#H bond acceptors: 8; (2)#H bond donors: 2; (3)Polar Surface Area: 108.92Å²; (4)H-Bond Acceptor: 8; (5)Tautomer Count: 3; (6)Exact Mass: 569.103492; (7)MonoIsotopic Mass: 569.103492; (8)Topological Polar Surface Area: 53.4; (9)Heavy Atom Count: 41; (10)Formal Charge: -4; (11)Complexity: 1310; (12)Undefined Atom StereoCenter Count: 2; (13)Undefined Bond StereoCenter Count: 4; (14)Covalently-Bonded Unit Count: 2.

You can still convert the following datas into molecular structure:
(1)SMILES: [Mn+2].n1c2nc8nc(nc6nc(nc5nc(nc1c3ccccc23)c4ccccc45)c7ccccc67)c9ccccc89
(2)InChI: InChI=1/C32H18N8.Mn/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H,(H2,33,34,35,36,37,38,39,40);/q;+2
(3)InChIKey: IWZYXAUFAANREW-UHFFFAOYAA
(4)Std. InChI: InChI=1S/C32H18N8.Mn/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H,(H2,33,34,35,36,37,38,39,40);/q;+2
(5)Std. InChIKey: IWZYXAUFAANREW-UHFFFAOYSA-N

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