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Cas Database |
| Name |
Morpholin-4-ylacetic acid |
EINECS | N/A |
| CAS No. | 3235-69-6 | Density | 1.202 g/cm3 |
| PSA | 49.77000 | LogP | -0.65890 |
| Solubility | N/A | Melting Point |
162-164 °C |
| Formula | C6H11NO3 | Boiling Point | 271.898 °C at 760 mmHg |
| Molecular Weight | 145.158 | Flash Point | 118.24 °C |
| Transport Information | N/A | Appearance | N/A |
| Safety | Risk Codes | 36 | |
| Molecular Structure |
|
Hazard Symbols |
 Xi
|
| Synonyms |
2-(4-Morpholinyl)aceticacid;2-(Morpholino)acetic acid;Morpholinoacetic acid;N-(Carboxymethyl)morpholine; |
Article Data | 32 |
Morpholin-4-ylacetic acid Synthetic route
- 88217-68-9
(4-morpholinyl)acetic acid 1,1-dimethylethyl ester
- 3235-69-6
morpholin-4-ylacetic acid
| Conditions | Yield |
|---|---|
| With potassium tert-butylate In tetrahydrofuran at 0℃; for 0.5h; Hydrolysis; | 100% |
| In water; isopropyl alcohol at 160℃; for 0.4h; Solvent; Temperature; Flow reactor; | 95% |
| With trifluoroacetic acid In dichloromethane at 20℃; for 5h; |
- 53342-23-7
benzyl morpholino-acetate
- 3235-69-6
morpholin-4-ylacetic acid
| Conditions | Yield |
|---|---|
| With hydrogen; palladium on activated charcoal In methanol for 40h; | 98% |
| With potassium tert-butylate In tetrahydrofuran at 0℃; for 5h; Hydrolysis; | 97% |
| Conditions | Yield |
|---|---|
| With hydrogenchloride In water at 95℃; for 16h; Temperature; Time; | 96.3% |
| With water for 30h; Hydrolysis; Heating; | 87% |
| With sodium hydroxide In water Heating; | 65% |
- 35855-10-8
methyl 2-morpholin-4-ylacetate
- 3235-69-6
morpholin-4-ylacetic acid
| Conditions | Yield |
|---|---|
| Stage #1: methyl 2-morpholin-4-ylacetate With methanol; sodium hydroxide; water In tetrahydrofuran at 50℃; for 1h; Stage #2: With hydrogenchloride In tetrahydrofuran; water pH=3; | 90% |
| With water; lithium hydroxide In methanol at 20℃; for 3h; Inert atmosphere; |
| Conditions | Yield |
|---|---|
| With potassium carbonate In N,N-dimethyl-formamide at 20℃; Inert atmosphere; | 85.3% |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran; hydrogenchloride; ethyl acetate | 85% |
| In tetrahydrofuran; hydrogenchloride; ethyl acetate | 85% |
- 110-91-8
morpholine
- 5625-90-1
4-(morpholinomethyl)morpholine
- 151-50-8
potassium cyanide
- 3235-69-6
morpholin-4-ylacetic acid
| Conditions | Yield |
|---|---|
| With water |
| Conditions | Yield |
|---|---|
| With water |
A
- 3235-69-6
morpholin-4-ylacetic acid
| Conditions | Yield |
|---|---|
| With hydrogenchloride; water In acetic acid at 69.9 - 95.9℃; Rate constant; Kinetics; Thermodynamic data; ΔS(activ.), ΔH(activ.), ΔG(activ.); |
| Conditions | Yield |
|---|---|
| With sodium hydroxide In 1,4-dioxane; benzene |
Morpholin-4-ylacetic acid Chemical Properties
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Molecular Formula: C6H11NO3
Molecular Weight: 145.16 g/mol
Canonical SMILES: O=C(O)CN1CCOCC1
InChI: InChI=1/C6H11NO3/c8-6(9)5-7-1-3-10-4-2-7/h1-5H2,(H,8,9)
Mol File: 3235-69-6.mol
Product Categories: Amino Acids and Derivatives
Nominal Mass: 145
Average Mass: 145.1564
Monoisotopic Mass: 145.073893
H bond acceptors: 4
H bond donors: 1
#Freely Rotating Bonds: 2
Polar Surface Area: 38.77
Index of Refraction: 1.483
Molar Refractivity: 34.5 cm3
Molar Volume: 120.7 cm3
Polarizability: 13.68×10-24cm3
Surface Tension: 43.1 dyne/cm
Density: 1.202 g/cm3
Flash Point: 118.2 °C
Enthalpy of Vaporization: 56.15 kJ/mol
Boiling Point: 271.9 °C at 760 mmHg
Vapour Pressure of 4-Morpholineacetic acid (CAS NO.3235-69-6): 0.00175 mmHg at 25 °C
Morpholin-4-ylacetic acid Safety Profile
Hazard Codes: 
Xi
HazardClass of 4-Morpholineacetic acid (CAS NO.3235-69-6): Irritant
Morpholin-4-ylacetic acid Specification
4-Morpholineacetic acid (CAS NO.3235-69-6), its synonyms are 2-(4-Morpholinyl)acetic acid ;
Morpholineacetic acid ; Morpholin-4-yl-acetic acid ; 4-Morpholine acetic acid .
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