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N-(3-Triethoxysilylpropyl)ethylenediamine

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Name

N-(3-Triethoxysilylpropyl)ethylenediamine

EINECS 225-806-1
CAS No. 5089-72-5 Density 0.953 g/cm3
PSA 65.74000 LogP 2.06440
Solubility 240g/L at 20℃ Melting Point 135 °C at 5 mmHg
Formula C11H28N2O3Si Boiling Point 308.742 °C at 760 mmHg
Molecular Weight 264.44 Flash Point 140.522 °C
Transport Information N/A Appearance Colorless clear liquid
Safety 26-36/37/39 Risk Codes 36/37/38
Molecular Structure Molecular Structure of 5089-72-5 (N-(3-Triethoxysilylpropyl)ethylenediamine) Hazard Symbols N/A
Synonyms

Aminoethylaminopropyltriethoxysilane;GF 90 (amine);Geniosil GF 94;N-(2-Aminoethyl)-3-aminopropyltriethoxysilane;N-(b-Aminoethyl)-g-aminopropyltriethoxysilane;SH 6026;Silquest Y 11763;[3-[(2-Aminoethyl)amino]propyl]triethoxysilane;1,2-Ethanediamine,N-[3-(triethoxysilyl)propyl]- (9CI);(g-Ethylenediaminepropyl)triethoxysilane;3-(2-Aminoethylamine)propyltriethoxysilane;1,2-Ethanediamine,N1-[3-(triethoxysilyl)propyl]-;

 

N-(3-Triethoxysilylpropyl)ethylenediamine Synthetic route

5089-70-3

(3-chloropropyl)triethoxysilane

107-15-3

ethylenediamine

5089-72-5

3-[N-(2-aminoethyl)]aminopropyltriethoxysilane

5089-72-5

3-[N-(2-aminoethyl)]aminopropyltriethoxysilane

1148-11-4

N-Benzyloxycarbonyl-L-proline

502186-02-9

N,N'-bis[(S)-N-benzyloxycarbonylprolyl]-N-(2-aminoethyl-3-aminopropyl)triethoxysilylethylenediamine

Conditions
ConditionsYield
Stage #1: N-Benzyloxycarbonyl-L-proline With chloroformic acid ethyl ester; triethylamine In tetrahydrofuran at 5 - 10℃; for 0.5h;
Stage #2: 3-[N-(2-aminoethyl)]aminopropyltriethoxysilane In tetrahydrofuran at 0℃; for 1h;
96%
102-71-6

triethanolamine

5089-72-5

3-[N-(2-aminoethyl)]aminopropyltriethoxysilane

52035-79-7

N-[3-(2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undec-1-yl)-propyl]-ethane-1,2-diamine

Conditions
ConditionsYield
95.4%
18279-61-3

trimethylsilyl diethylcarbamate

5089-72-5

3-[N-(2-aminoethyl)]aminopropyltriethoxysilane

1230037-31-6

2,2-dimethoxy-1,6,9,2-oxadiazasilecane

Conditions
ConditionsYield
Inert atmosphere; Reflux;95%
1118-02-1

trimethylsilyl isocyanate

5089-72-5

3-[N-(2-aminoethyl)]aminopropyltriethoxysilane

1230037-60-1

trimethylsilyl-N'-[(E)-7,7,17,17-tetramethoxy-9-oxo-18-oxa-3,8,10,13-tetraaza-7,17-disilanonadec-1-yl]imidocarbamate

Conditions
ConditionsYield
Reflux; Inert atmosphere;94%
5089-72-5

3-[N-(2-aminoethyl)]aminopropyltriethoxysilane

920-46-7

Methacryloyl chloride

N-methacryloyl-N-(2-(N-(3-(triethoxysilyl)propyl)methacrylamido)ethyl)methacrylamide

Conditions
ConditionsYield
Stage #1: 3-[N-(2-aminoethyl)]aminopropyltriethoxysilane With trimethylamine In dichloromethane for 0.166667h; Cooling with ice; Inert atmosphere;
Stage #2: Methacryloyl chloride In dichloromethane at 20℃; for 8h; Cooling with ice; Inert atmosphere;
92.8%
5089-72-5

3-[N-(2-aminoethyl)]aminopropyltriethoxysilane

814-68-6

acryloyl chloride

N-acryloyl-N-(2-(N-(3-(triethoxysilyl)propyl)acrylamido)ethyl)acrylamide

Conditions
ConditionsYield
Stage #1: 3-[N-(2-aminoethyl)]aminopropyltriethoxysilane With trimethylamine In dichloromethane for 0.166667h; Cooling with ice; Inert atmosphere;
Stage #2: acryloyl chloride In dichloromethane at 20℃; for 8h; Cooling with ice; Inert atmosphere;
92.4%
5089-72-5

3-[N-(2-aminoethyl)]aminopropyltriethoxysilane

31795-93-4

N-benzyl-L-proline

479677-97-9

N,N'-bis[(S)-N-benzylprolyl]-N-(2-aminoethyl-3-aminopropyl)triethoxysilylethylenediamine

Conditions
ConditionsYield
Stage #1: N-benzyl-L-proline With chloroformic acid ethyl ester; triethylamine In tetrahydrofuran at 5 - 10℃; for 0.5h;
Stage #2: 3-[N-(2-aminoethyl)]aminopropyltriethoxysilane In tetrahydrofuran at 0℃; for 1h;
90%
5089-72-5

3-[N-(2-aminoethyl)]aminopropyltriethoxysilane

1592-20-7

4-Vinylbenzyl chloride

C20H36N2O3Si

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol In cyclohexane at 50 - 90℃; for 2h;90%
5089-72-5

3-[N-(2-aminoethyl)]aminopropyltriethoxysilane

24801-88-5

3-(triethoxypropyl) isocyanate

C21H49N3O7Si2

Conditions
ConditionsYield
In acetone at 65℃; for 12h;

N-(3-Triethoxysilylpropyl)ethylenediamine Specification

The N-(3-Triethoxysilylpropyl)ethylenediamine, with the CAS registry number 5089-72-5, is also known as 3-(2-Aminoethylamine)propyltriethoxysilane. It belongs to the product categories of Amino; Amino Silanes (Silane Coupling Agents); Functional Materials; Si (Classes of Silicon Compounds); Silane Coupling Agents; Si-O Compounds; Trialkoxysilanes; Amino Silanes. Its EINECS number is 225-806-1. This chemical's molecular formula is C11H28N2O3Si and molecular weight is 264.44. What's more, its systematic name is N-[3-(Triethoxysilyl)propyl]-1,2-ethanediamine. It is stable at common pressure and temperature, and it should be sealed and stored in a cool and dry place. Moreover, it should be protected from light. Its storage temperature is below 5° C. This chemical is used in the coupling of thermosetting resins such as epoxy, phenolic aldehyde, melamine and hot-fusible resins such as polystyrene, polyamide.

Physical properties of N-(3-Triethoxysilylpropyl)ethylenediamine are: (1)ACD/LogP: 2.176; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -1.66; (4)ACD/LogD (pH 7.4): -0.48; (5)ACD/BCF (pH 5.5): 1.00; (6)ACD/BCF (pH 7.4): 1.00; (7)ACD/KOC (pH 5.5): 1.00; (8)ACD/KOC (pH 7.4): 1.00; (9)#H bond acceptors: 5; (10)#H bond donors: 3; (11)#Freely Rotating Bonds: 13; (12)Polar Surface Area: 65.74 Å2; (13)Index of Refraction: 1.447; (14)Molar Refractivity: 74.093 cm3; (15)Molar Volume: 277.427 cm3; (16)Polarizability: 29.373×10-24cm3; (17)Surface Tension: 29.21 dyne/cm; (18)Density: 0.953 g/cm3; (19)Flash Point: 140.522 °C; (20)Enthalpy of Vaporization: 54.944 kJ/mol; (21)Boiling Point: 308.742 °C at 760 mmHg; (22)Vapour Pressure: 0.001 mmHg at 25°C.

Uses of N-(3-Triethoxysilylpropyl)ethylenediamine: it can be used to produce N-[3-(2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undec-1-yl)-propyl]-ethane-1,2-diamine. The yield is about 95.4%.

N-(3-Triethoxysilylpropyl)ethylenediamine can be used to produce N-[3-(2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undec-1-yl)-propyl]-ethane-1,2-diamine

When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. When using it, you need to wear suitable protective clothing, gloves and eye/face protection.

You can still convert the following datas into molecular structure:
(1)SMILES: O(CC)[Si](OCC)(OCC)CCCNCCN
(2)Std. InChI: InChI=1S/C11H28N2O3Si/c1-4-14-17(15-5-2,16-6-3)11-7-9-13-10-8-12/h13H,4-12H2,1-3H3
(3)Std. InChIKey: INJVFBCDVXYHGQ-UHFFFAOYSA-N 

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