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Cas Database

Name	N-Isopropylhydroxylamine	EINECS	225-791-1
CAS No.	5080-22-8	Density	0.886 g/cm³
PSA	32.26000	LogP	0.76450
Solubility	199g/L at 25℃	Melting Point	159-160 °C (dec.)
Formula	C₃H₉NO	Boiling Point	104.9 °C at 760 mmHg
Molecular Weight	75.1106	Flash Point	44.5 °C
Transport Information	N/A	Appearance	N/A
Safety	24/25	Risk Codes	21/22
Molecular Structure		Hazard Symbols	Xn
Synonyms	Hydroxylamine,N-isopropyl- (6CI,7CI,8CI);Isopropylhydroxylamine;N-Hydroxy-2-propanamine;	Article Data	29

N-Isopropylhydroxylamine Synthetic route

: 113768-49-3
2-Isopropyl-3-methyl-5-oxo-2,5-dihydro-isoxazole-4-carboxylic acid ethyl ester

: 5080-22-8
N-isopropylhydroxyamine

Conditions

Conditions	Yield
With hydrogenchloride; acetic acid In water	96%

: 79-46-9
2-nitropropane

A: 75-31-0
isopropylamine

B: 5080-22-8
N-isopropylhydroxyamine

Conditions

Conditions	Yield
With hydrogen In para-xylene; isopropyl alcohol at 25℃; under 760.051 Torr; for 4h;	A 9% B 88%

: 79-46-9
2-nitropropane

: 5080-22-8
N-isopropylhydroxyamine

Conditions

Conditions	Yield
With ammonia borane; gold on titanium oxide In ethanol at 20℃; for 0.666667h; Inert atmosphere;	85%
elektrochemische Reduktion;
With ammonia; sodium at -33.5℃;

: 7647-01-0
hydrogenchloride

: 3-nitro-benzaldehyde-(N-isopropyl oxime )

A: 99-61-6
3-nitro-benzaldehyde

B: 5080-22-8
N-isopropylhydroxyamine

m-nitro-N-isopropyl-isobenzaldoxime: m-nitro-N-isopropyl-isobenzaldoxime

A: 99-61-6
3-nitro-benzaldehyde

B: 5080-22-8
N-isopropylhydroxyamine

Conditions

Conditions	Yield
With hydrogenchloride

: 79-46-9
2-nitropropane

: 7664-41-7
ammonia

sodium: sodium

: 5080-22-8
N-isopropylhydroxyamine

: 7647-01-0
hydrogenchloride

: 127-06-0
acetone oxime

platinum black: platinum black

A: 5765-61-7
N,N-diisopropylhydroxylamine

B: 5080-22-8
N-isopropylhydroxyamine

C N-isopropyl-hydroxylammonium chloride: N-isopropyl-hydroxylammonium chloride

D N.N-diisopropyl-hydroxylammonium chloride: N.N-diisopropyl-hydroxylammonium chloride

Conditions

Conditions	Yield
Hydrogenation;

...Expand

: 144-62-7
oxalic acid

: 127-06-0
acetone oxime

platinum black: platinum black

A: 5765-61-7
N,N-diisopropylhydroxylamine

B: 5080-22-8
N-isopropylhydroxyamine

C N-isopropyl-hydroxylammonium oxalate: N-isopropyl-hydroxylammonium oxalate

D N.N-diisopropyl-hydroxylammonium oxalate: N.N-diisopropyl-hydroxylammonium oxalate

Conditions

Conditions	Yield
Hydrogenation;

...Expand

: 127-06-0
acetone oxime

: 5080-22-8
N-isopropylhydroxyamine

Conditions

Conditions	Yield
Inert atmosphere;
Stage #1: acetone oxime With sodium cyanoborohydride In methanol at 20℃; for 4h; Stage #2: With hydrogenchloride In methanol

: 123-38-6
propionaldehyde

: 5080-22-8
N-isopropylhydroxyamine

: 107341-57-1, 118644-19-2, 118644-29-4
C6H13NO

Conditions

Conditions	Yield
In ethanol at 20℃; for 0.5h;	100%

N-Isopropylhydroxylamine Chemical Properties

The molecular structure of 2-Propanamine,N-hydroxy- (CAS NO.5080-22-8) is

IUPAC Name: N-Propan-2-ylhydroxylamine
Canonical SMILES: CC(C)NO
Molecular Formula: C₃H₉ N O
Molecular Weight: 75.11
EINECS: 225-791-1
Density: 0.886g/cm³
Melting Point: 159-160 °C (dec.)
Boiling Point: 104.9°C at 760mmHg
Flash Point: 44.5°C
Freely Rotating Bonds: 2
Polar Surface Area: 12.47 Å²
Index of Refraction: 1.41
Molar Refractivity: 21.03 cm³
Molar Volume: 84.7 cm³
Polarizability: 8.33× 10^-24 cm³
Surface Tension: 27.2 dyne/cm
Enthalpy of Vaporization: 40.09 kJ/mol
Vapour Pressure: 16.5 mmHg at 25°C
The Cas Register Number of 2-Propanamine,N-hydroxy- is 5080-22-8. The chemical synonyms of 2-Propanamine,N-hydroxy- (CAS NO.5080-22-8) are N-hydroxy-2-propanamin ; N-hydroxy-2-Propaneamine ; N-isopropylhydroxylamineoxalate ; IPHA ; N-Isopropylhydroxylamine ; N-Isopropylhydroxylamine oxalate salt ; 2-Propanamine, N-hydroxy- ; 2-hydroxylaminopropane .

N-Isopropylhydroxylamine Uses

2-Propanamine,N-hydroxy- (CAS NO.5080-22-8) is used in organic synthesis.

N-Isopropylhydroxylamine Safety Profile

Hazard Codes: Harmful Xn
Risk Statements: 21/22
R21/22: Harmful in contact with skin and if swallowed.
Safety Statements: 24/25
S24/25: Avoid contact with skin and eyes.

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