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Nickel sulfate hexahydrate

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Nickel sulfate hexahydrate

EINECS 231-111-4
CAS No. 10101-97-0 Density 2.07 g/cm3
PSA 144.02000 LogP -0.64300
Solubility soluble in water Melting Point 1453 °C(lit.)
Formula NiSO4.6(H2O) Boiling Point 330 °C at 760 mmHg
Molecular Weight 262.89 Flash Point N/A
Transport Information UN 3178 4.1/PG 2 Appearance Green crystals
Safety 53-45-61-60-36/37-22-36/37/39-26-16 Risk Codes 45-52/53-50/53-42/43-40-22-36/37-23/24/25-11-36/38
Molecular Structure Molecular Structure of 10101-97-0 (Nickel sulfate hexahydrate) Hazard Symbols ToxicT,IrritantXi,DangerousN,HarmfulXn,FlammableF
Synonyms

Sulfuricacid, nickel(2+) salt (1:1), hexahydrate (8CI,9CI);Nickel monosulfatehexahydrate;Nickel sulfate (NiSO4) hexahydrate;Nickel sulfate hydrate (NiSO4.6H2O);Nickel(2+) monosulfate hexahydrate;Nickel(2+) sulfate hexahydrate;Nickel(II) sulfate hexahydrate;Sulfuric acid,nickel(2+) salt, hydrate (1:1:6);

 

Nickel sulfate hexahydrate Consensus Reports

NTP 10th Report on Carcinogens. Nickel and its compounds are on the Community Right-To-Know List. EPA Genetic Toxicology Program.

Nickel sulfate hexahydrate Standards and Recommendations

OSHA PEL: TWA 0.1 mg (Ni)/m3
ACGIH TLV: TWA 0.2 mg(Ni)/m3; Human Carcinogen
NIOSH REL: (Inorganic Nickel) TWA 0.015 mg(Ni)/m3

Nickel sulfate hexahydrate Specification

The Nickel(II) sulfate hexahydrate (1:1:6) is an organic compound with the formula NiSO4.6(H2O). The IUPAC name of this chemical is nickel(2+) sulfate hexahydrate. With the CAS registry number 10101-97-0, it is also named as Sulfuric acid, nickel(2+) salt, hexahydrate. The product's categories are Chemical Synthesis; Metals; NickelMetal and Ceramic Science; Alternative Energy; Catalysis and Inorganic Chemistry; Fuel Cell Catalysts Chemical Synthesis; Materials Science; Analytical Reagents for General Use ;M-N, Puriss p.a. ACS; Puriss p.a. ACS; ACS GradeChemical Synthesis; Essential Chemicals; Routine Reagents; HIS Select Supporting Products and Reagents; HIS-Select; Reagents and Products for use with HIS-Select; Allergens; Extractable Heavy metals Application CRMs; ICP CRMsCosmetics; ICP-OES/-MS; ICPSpectroscopy; Matrix Selection; Metals Alphabetic; Method Specific; N; NA - NISpectroscopy; NitrateMore...Close...; Oeko-Tex Standard 100; Spectroscopy. Besides, it is a green crystal, which should be stored in a cool dry and ventilated place.

The Nickel(II) sulfate hexahydrate (1:1:6) is mainly used in electroplating industry, which is the main raw material of nickel. It is used to produce brilliant blue phthalocyanine complexing agent and restore mordant dyes in printing and dyeing industry. In pharmaceutical industry, it is used to produce catalyst of vitamin C.

Physical properties about Nickel(II) sulfate hexahydrate (1:1:6) are: (1)ACD/LogP: -1.03; (2)ACD/LogD (pH 5.5): -5.53; (3)ACD/LogD (pH 7.4): -5.53; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)ACD/KOC (pH 7.4): ; (7)#H bond acceptors: 4; (8)#H bond donors: 2; (9)Polar Surface Area: 82.98 Å2; (10)Enthalpy of Vaporization: 62.94 kJ/mol; (11)Boiling Point: 330 °C at 760 mmHg; (12)Vapour Pressure: 3.35E-05 mmHg at 25°C.

Preparation: this chemical can be prepared by Nickel-containing waste solution. Chemical reaction equation is as follows:

When you are using this chemical, please be cautious about it as the following:
It is highly flammable and harmful if swallowed. Please keep away from sources of ignition - No smoking and do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical may cause sensitisation by inhalation and skin contact and may cause cancer. It is very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment and harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. When you are using it, wear suitable gloves and eye/face protection and avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste.

You can still convert the following datas into molecular structure:
(1)SMILES: [Ni+2].[O-]S([O-])(=O)=O.O.O.O.O.O.O
(2)InChI: InChI=1/Ni.H2O4S.6H2O/c;1-5(2,3)4;;;;;;/h;(H2,1,2,3,4);6*1H2/q+2;;;;;;;/p-2
(3)InChIKey: RRIWRJBSCGCBID-NUQVWONBAU
(4)Std. InChI: InChI=1S/Ni.H2O4S.6H2O/c;1-5(2,3)4;;;;;;/h;(H2,1,2,3,4);6*1H2/q+2;;;;;;;/p-2
(5)Std. InChIKey: RRIWRJBSCGCBID-UHFFFAOYSA-L

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LDLo intravenous 71600ug/kg (71.6mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
cat LDLo subcutaneous 500mg/kg (500mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
dog LDLo intravenous 89500ug/kg (89.5mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
guinea pig LDLo subcutaneous 62mg/kg (62mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rabbit LDLo intravenous 35800ug/kg (35.8mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rabbit LDLo subcutaneous 500mg/kg (500mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rat LD50 oral 264mg/kg (264mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS

GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"
Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 1, Pg. 685, 1992.

 

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