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Cas Database

Name	PHENYL CARBITOL	EINECS	N/A
CAS No.	104-68-7	Density	1.092g/cm³
PSA	38.69000	LogP	1.07430
Solubility	35g/L at 20℃	Melting Point	-49.9°C
Formula	C10H14 O3	Boiling Point	309.3°Cat760mmHg
Molecular Weight	182.219	Flash Point	140.9°C
Transport Information	N/A	Appearance	N/A
Safety	Moderately toxic by ingestion and skin contact. A skin and severe eye irritant. Some glycol ethers have dangerous human reproductive effects. When heated to decomposition it emits acrid smoke and irritating fumes. See also GLYCOL ETHERS.	Risk Codes	N/A
Molecular Structure		Hazard Symbols	N/A
Synonyms	2-(2-Phenoxyethoxy)ethanol;Diethylene glycol monophenyl ether; Diethylene glycol phenyl ether; NSC 406593;Phenoxydiglycol; Phenyl Di Glycol; Phenyl carbitol; Sunfine PH 20	Article Data	14

PHENYL CARBITOL Synthetic route

: 57641-66-4
2-(2-bromoethoxy)ethan-1-ol

: 108-95-2
phenol

: 104-68-7
2-(2-phenoxyethoxy)ethanol

Conditions

Conditions	Yield
Stage #1: phenol With potassium hydroxide In acetonitrile at 60℃; for 2h; Inert atmosphere; Stage #2: 2-(2-bromoethoxy)ethan-1-ol With potassium iodide In acetonitrile at 60℃; for 10h; Inert atmosphere;	72%

: 108-86-1
bromobenzene

: 62-53-3
aniline

: 111-46-6
diethylene glycol

A: 104-68-7
2-(2-phenoxyethoxy)ethanol

B: 122-39-4
diphenylamine

Conditions

Conditions	Yield
With copper(II) acetate monohydrate; potassium carbonate at 110℃; for 8h; Catalytic behavior; Reagent/catalyst; Inert atmosphere;	A 28% B 70%

: 75-21-8
oxirane

: 139-02-6
sodium phenoxide

: 104-68-7
2-(2-phenoxyethoxy)ethanol

Conditions

Conditions	Yield
at 95℃; for 2h;	69%

: 108-86-1
bromobenzene

: 100-01-6
4-nitro-aniline

: 111-46-6
diethylene glycol

A: 836-30-6
4-ntrophenyl(phenyl)amine

B: 104-68-7
2-(2-phenoxyethoxy)ethanol

Conditions

Conditions	Yield
With copper(II) acetate monohydrate; potassium carbonate at 110℃; for 20h; Inert atmosphere;	A 68% B 22%

: 108-86-1
bromobenzene

: 111-46-6
diethylene glycol

: 104-68-7
2-(2-phenoxyethoxy)ethanol

Conditions

Conditions	Yield
With N-Methyldicyclohexylamine; C46H67BN2; nickel dibromide In N,N-dimethyl-formamide at 60℃; for 24h;	65%

: 108-86-1
bromobenzene

: 95-53-4
o-toluidine

: 111-46-6
diethylene glycol

A: 104-68-7
2-(2-phenoxyethoxy)ethanol

B: 1205-39-6
N-phenyl-2-methylaniline

Conditions

Conditions	Yield
With copper(II) acetate monohydrate; potassium carbonate at 110℃; for 12h; Inert atmosphere;	A 33% B 63%

: 108-86-1
bromobenzene

: 24544-04-5
2,6-diisopropylbenzenamine

: 111-46-6
diethylene glycol

A: 104-68-7
2-(2-phenoxyethoxy)ethanol

B: (2,6-diisopropyl-N-phenyl)phenylamine

Conditions

Conditions	Yield
With copper(II) acetate monohydrate; potassium carbonate at 110℃; for 20h; Inert atmosphere;	A 30% B 11%

: 75-21-8
oxirane

: 108-95-2
phenol

: 104-68-7
2-(2-phenoxyethoxy)ethanol

Conditions

Conditions	Yield
With sodium phenoxide at 200℃;

: 139-02-6
sodium phenoxide

: 108-95-2
phenol

: 104-68-7
2-(2-phenoxyethoxy)ethanol

Conditions

Conditions	Yield
at 100℃; Einleiten von Aethylenoxyd;

: 31603-33-5
bis(phenoxyethoxyethyl) peroxydicarbonate

A: 124-38-9
carbon dioxide

B: 622-87-7
β,β'-Bis(phenoxyethyl)ether

C: 104-68-7
2-(2-phenoxyethoxy)ethanol

D: 141-46-8
Glycolaldehyde

E: Carbonic acid 2-hydroxy-1-(2-phenoxy-ethoxy)-ethyl ester 2-(2-phenoxy-ethoxy)-ethyl ester

Conditions

Conditions	Yield
In benzene at 60℃; Rate constant; Kinetics; var. temp., also with inhibiting addition of styrene or α-naphthol, Eact;

...Expand

PHENYL CARBITOL Chemical Properties

MF: C₁₀H₁₄O₃
MW: 182.21636
EINECS: 203-227-5

PHENYL CARBITOL Toxicity Data With Reference

1.	skn-rbt 505 mg open MLD	UCDS** Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 8/16 ,1961.
2.	eye-rbt 2 mg open SEV	AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
3.	orl-rat LD50:2140 mg/kg	AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
4.	skn-rbt LD50:2120 mg/kg	UCDS** Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 8/16 ,1961.

RTECS: KM0875000

PHENYL CARBITOL Consensus Reports

Glycol ether compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

PHENYL CARBITOL Safety Profile

Moderately toxic by ingestion and skin contact. A skin and severe eye irritant. Some glycol ethers have dangerous human reproductive effects. When heated to decomposition it emits acrid smoke and irritating fumes. See also GLYCOL ETHERS.

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