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Phosphine, cyclohexyl-

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Name

Phosphine, cyclohexyl-

EINECS N/A
CAS No. 822-68-4 Density 0,875 g/cm3
PSA 13.59000 LogP 2.19420
Solubility N/A Melting Point N/A
Formula C6H13P Boiling Point 145 °C at 760 mmHg
Molecular Weight 116.143 Flash Point 41.5 °C
Transport Information UN 3185 Appearance colourless liquid with an offensive odour
Safety 9-16-26-36/37/39 Risk Codes 17-20/21/22-34
Molecular Structure Molecular Structure of 822-68-4 (CYCLOHEXYLPHOSPHINE) Hazard Symbols N/A
Synonyms

Cyclohexylphosphine;

Article Data 14

Phosphine, cyclohexyl- Synthetic route

2310-71-6

dicyclohexylphosphonous acid

A

1005-23-8

cyclohexylphosphonic acid

B

822-68-4

cyclohexylphosphine

Conditions
ConditionsYield
at 250℃; Yields of byproduct given;A n/a
B 46.13%
With water 1) 250 deg C, 2) reflux; Yield given. Multistep reaction. Yields of byproduct given;
79564-48-0

Monoethoxicarbonylcyclohexylphosphan

A

64-17-5

ethanol

B

822-68-4

cyclohexylphosphine

C

CO2

CO2

Conditions
ConditionsYield
With hydrogenchloride for 4h; Product distribution; Heating; reaction with KOH;A n/a
B 33%
C n/a
1005-22-7

cyclohexylphosphonic dichloride

822-68-4

cyclohexylphosphine

Conditions
ConditionsYield
With lithium aluminium tetrahydride; diethyl ether
With sodium; toluene
110-83-8

cyclohexene

822-68-4

cyclohexylphosphine

Conditions
ConditionsYield
With phosphan Irradiation;
With 2,2'-azobis(isobutyronitrile); phosphan at 78 - 80℃; for 3.5h;
110-83-8

cyclohexene

phosphine

phosphine

822-68-4

cyclohexylphosphine

Conditions
ConditionsYield
UV-Licht.Irradiation;
80984-31-2

Os3(CO)11P(C6H11)H2

822-68-4

cyclohexylphosphine

Conditions
ConditionsYield
In toluene 100°C, 24 h; vac. evapd., chromd. on silica gel with 5/1 pentane/toluene;60-66
2844-89-5

dichlorocyclohexylphosphine

822-68-4

cyclohexylphosphine

Conditions
ConditionsYield
Stage #1: dichlorocyclohexylphosphine With sodium In 1,4-dioxane at 110℃; Inert atmosphere;
Stage #2: With acetic acid In diethyl ether at -10 - 0℃; for 5h; Inert atmosphere;
31080-62-3

diisopropylallylphosphonite

822-68-4

cyclohexylphosphine

850716-19-7

C6H11P(C3H6P(OCH(CH3)2)2)2

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) at 20℃; for 48h; Irradiation;100%
822-68-4

cyclohexylphosphine

dimethylallylphosphonite

850716-21-1

C6H11P(C3H6P(OCH3)2)2

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) at 20℃; for 48h; Irradiation;100%
109-64-8

1,3-dibromo-propane

822-68-4

cyclohexylphosphine

97472-13-4

1,3-bis(cyclohexylphosphanyl)propane

Conditions
ConditionsYield
Stage #1: cyclohexylphosphine With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.333333h; Inert atmosphere;
Stage #2: 1,3-dibromo-propane In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere;
100%

Phosphine, cyclohexyl- Specification

This chemical is called Phosphine, cyclohexyl-, and its CAS registry number is 822-68-4. With the molecular formula of C6H13P, its product category is Primary Phosphines. It's incompatible with organic material, air, oxidizing agents, halogens. Store it under an inert atmosphere.

Other characteristics of the Phosphine, cyclohexyl- can be summarised as followings: (1)#H bond acceptors: 0; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 1; (4)Polar Surface Area: 13.59 Å2; (5)Flash Point: 41.5 °C; (6)Enthalpy of Vaporization: 36.63 kJ/mol; (7)Boiling Point: 145 °C at 760 mmHg; (8)Vapour Pressure: 6.25 mmHg at 25°C.

Uses of this chemical: The Phosphine, cyclohexyl- could react with 3-chlorocarbonyloxy-propene, and obtain the Monoallyloxycarbonyl-cyclohexylphosphan. This reaction needs the reagent of K2CO3, and the solvent of benzene. The yield is 73.7 %. In addition, this reaction should be taken for 6 hours. The other condition is heating.

The Phosphine, cyclohexyl- could react with 3-chlorocarbonyloxy-propene, and obtain the Monoallyloxycarbonyl-cyclohexylphosphan

When you are using this chemical, please be cautious about it as the following: This chemical is spontaneously flammable in air. Keep it away from sources of ignition. It's harmful by inhalation, in contacting with skin and if swallowed. It causes burns. Wear suitable protective clothing, gloves and eye/face protection. In case of contacting with eyes, rinse immediately with plenty of water and seek medical advice. Keep the container in a well-ventilated place.

You can still convert the following datas into molecular structure: 
1.SMILES: PC1CCCCC1
2.InChI: InChI=1/C6H13P/c7-6-4-2-1-3-5-6/h6H,1-5,7H2
3.InChIKey: ZBCKWHYWPLHBOK-UHFFFAOYAG

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