Welcome to LookChem.com Sign In|Join Free
  • or
Home > Products >  > 

Phosphorus trifluoride

Related Products

Hot Products

Name

Phosphorus trifluoride

EINECS 232-008-7
CAS No. 7783-55-3 Density 3.91 g/L, gas
PSA 13.59000 LogP 2.12180
Solubility slow hydrolysis in water Melting Point -151.5 °C, 122 K, -241 °F
Formula F3P Boiling Point -101.8 °C, 171 K, -151 °F
Molecular Weight 87.969 Flash Point -101.5°C
Transport Information N/A Appearance N/A
Safety 3/7-9-38-45 Risk Codes 14-32-34
Molecular Structure Molecular Structure of 7783-55-3 (PHOSPHORUS TRIFLUORIDE) Hazard Symbols ToxicT
Synonyms

Phosphorusfluoride (PF3) (6CI,8CI);Phosphorus trifluoride;Trifluorophosphine;trifluorophosphin;

Article Data 157

Phosphorus trifluoride Synthetic route

1279123-63-5

potassium hydrogenfluoride

7789-60-8

phosphorus tribromide

7783-55-3

trifluorophosphane

Conditions
ConditionsYield
In acetonitrile byproducts: KBr, HBr; PBr3 in MeCN was slowly added to a boiling suspn. of KHF2 in MeCN;; the gaseous prod. was condensed in trap cooled by liq. N2 and distd. at -100°C; elem. anal.; IR;90%
1279123-63-5

potassium hydrogenfluoride

7719-12-2, 52843-90-0

phosphorus trichloride

7783-55-3

trifluorophosphane

Conditions
ConditionsYield
In acetonitrile byproducts: KCl, HCl; PCl3 in MeCN was slowly added to a boiling suspn. of KHF2 in MeCN;; the gaseous prod. was condensed in trap cooled by liq. N2 and distd. at -100°C; elem. anal.; IR;87.7%
14791-57-2

silyl bromide

34326-59-5

bis(difluorophosphino)amine

75-50-3

trimethylamine

A

11128-24-8

fluorosilane

B

71579-72-1

bis(difluorophosphine)silylamine

C

7783-55-3

trifluorophosphane

Conditions
ConditionsYield
In neat (no solvent) byproducts: (NHMe3)Br; absence of air and moisture (vac. line); condensing NMe3 onto mixt. of NH(PF2)2 and SiBrH3, warming to room temp. for 15 s; fractional distn.;A n/a
B 87%
C n/a

bis(trifluoromethyl)cadmium*(pyridine)2

13455-01-1

phosphorous triiodide

7783-55-3

trifluorophosphane

Conditions
ConditionsYield
In pyridine69%
14335-40-1

chlorodifluorophosphine

7664-41-7

ammonia

A

25757-74-8

aminodifluorophosphine

60448-09-1

diaminodifluorophosphorane

C

7783-55-3

trifluorophosphane

Conditions
ConditionsYield
In neat (no solvent) expanding excess of NH3 into PClF2, standing for 3 min; removal of volatiles, fractional low-temp. distn. (vac., trap at 227 K);mass spectroscopy;A n/a
B 42%
C n/a

fluoride

7719-12-2, 52843-90-0

phosphorus trichloride

7783-55-3

trifluorophosphane

Conditions
ConditionsYield
In melt passing PCl3 vapour into a melt of alkali fluorides at 500°C;;20%

phosphorous

7664-39-3

hydrogen fluoride

7783-55-3

trifluorophosphane

Conditions
ConditionsYield
500°C, closed reactor;5%
In not given heating red P with Hf under pressure;;

phosphorous

13465-66-2, 271781-78-3

selenium(IV) fluoride

A

7446-08-4

selenium(IV) oxide

B

13478-20-1

trifluorophosphoric acid

C

1087413-67-9

nitrosylsulfuric acid fluoride

D

7783-55-3

trifluorophosphane

ammonium fluoride

7719-12-2, 52843-90-0

phosphorus trichloride

A

15597-63-4

phosphorus fluoride dichloride

B

7783-55-3

trifluorophosphane

Conditions
ConditionsYield
In neat (no solvent) refluxing with dry NH4F;;
In neat (no solvent) heating PCl3 with dry NH4F with a reflux condenser;;
In neat (no solvent) refluxing with dry NH4F;;
In neat (no solvent) heating PCl3 with dry NH4F with a reflux condenser;;

calcium fluoride

phosphorus pentoxide

7647-14-5

sodium chloride

A

13478-20-1

trifluorophosphoric acid

B

13769-76-1

phosphoryl dichloride fluoride

C

13769-75-0

phosphorus oxydifluorochloride

D

7783-55-3

trifluorophosphane

Conditions
ConditionsYield
In neat (no solvent) heating with CaF2 in presence of NaCl;;
In neat (no solvent) heating with CaF2 in presence of NaCl;;

Phosphorus trifluoride Consensus Reports

Reported in EPA TSCA Inventory.

Phosphorus trifluoride Standards and Recommendations

OSHA PEL: TWA 2.5 mg(F)/m3
ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift.
NIOSH REL: (Fluorides, Inorganic) TWA 2.5 mg(F)/m3

Phosphorus trifluoride Specification

The Phosphorus trifluoride, with the CAS registry number 7783-55-3  and EINECS registry number 232-008-7, is also called trifluorophosphin. It is a kind of moisture sensitive chemical, and the molecular formula of this chemical is F3P. What's more, it is a colorless and odorless gas and main use is as a ligand in metal complexes.

The physical properties of Phosphorus trifluoride are as following: (1)ACD/LogP: 3.05; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 3.05; (4)ACD/LogD (pH 7.4): 3.05; (5)ACD/BCF (pH 5.5): 123.29; (6)ACD/BCF (pH 7.4): 123.29; (7)#H bond acceptors: 0; (8)#H bond donors: 0; (9)#Freely Rotating Bonds: 0; (10)Polar Surface Area: 13.59 Å2; (11)Enthalpy of Vaporization: 16.5 kJ/mol; (12)Boiling Point: °C at 760 mmHg; (13)Vapour Pressure: 40800 mmHg at 25°C.

Preparation of Phosphorus trifluoride: It is usually prepared from phosphorus trichloride via halogen exchange using various fluorides such as hydrogen fluoride, calcium fluoride, arsenic trifluoride, antimony trifluoride, or zinc fluoride:
2 PCl3 + 3 ZnF2 → 2 PF3 + 3 ZnCl2

You should be cautious while dealing with this chemical. It reacts violently with water, and if contact with acids will liberate very toxic gas. And it may also cause burns. Therefore, you had better take the following instructions: Keep container tightly closed in a cool place; Keep container in a well-ventilated place; In case of insufficient ventilation, wear suitable respiratory equipment; In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). In addition, its toxicity is due to its binding with the iron in blood hemoglobin in a similar way to carbon monoxide.

You can still convert the following datas into molecular structure:
(1)SMILES: FP(F)F
(2)InChI: InChI=1/F3P/c1-4(2)3
(3)InChIKey: WKFBZNUBXWCCHG-UHFFFAOYAK

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LCLo inhalation 1900mg/m3/10M (1900mg/m3)   National Defense Research Committee, Office of Scientific Research and Development, Progress Report.Vol. NDCrc-132, Pg. JUN1942,

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 7783-55-3