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Potassium hexafluorosilicate

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Potassium hexafluorosilicate

EINECS 240-896-2
CAS No. 16871-90-2 Density 2.665 g/mL at 25 °C(lit.)
PSA 0.00000 LogP 2.14040
Solubility slightly soluble in water Melting Point °Cd ec.)
Formula F6K2Si Boiling Point dec
Molecular Weight 364.474 Flash Point N/A
Transport Information UN 2655 6.1/PG 3 Appearance white, odorless crystalline powder
Safety 26-45 Risk Codes 23/24/25
Molecular Structure Molecular Structure of 16871-90-2 (Potassium fluorosilicate) Hazard Symbols ToxicT,IrritantXi
Synonyms

Potassiumfluosilicate (6CI);Silicate(2-), hexafluoro-, dipotassium (8CI,9CI);Potassium fluorosilicate (K2SiF6);Potassium hexafluorosilicate (K2SiF6);Potassiumsilicofluoride;Potassium silicon fluoride(K2SiF6);Potassium hexafluorosilicate;

Article Data 16

Potassium hexafluorosilicate Consensus Reports

Reported in EPA TSCA Inventory.

Potassium hexafluorosilicate Standards and Recommendations

OSHA PEL: TWA 2.5 mg(F)/m3
ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift.
NIOSH REL: TWA (Inorganic Fluorides) 2.5 mg(F)/m3
DOT Classification:  6.1; Label: KEEP AWAY FROM FOOD

Potassium hexafluorosilicate Specification

Potassium hexafluorosilicate(CAS NO.16871-90-2) has the synonyms of Potassium fluosilicate; Potassium silicofluoride; Silicate(2-), hexafluoro-, dipotassium; Silicate(2-), hexafluoro-, potassium (1:2). has weak oxidizing or reducing powers. Redox reactions can however still occur. The majority of compounds in this class are slightly soluble or insoluble in water. If soluble in water, then the solutions are usually neither strongly acidic nor strongly basic. These compounds are not water-reactive. Potassium hexafluorosilicate is mainly used for the preservation of timber, ceramics manufacturing, aluminum and magnesium smelting,optical glass manufacturing,etc.

You can still convert the following datas into molecular structure:
(1)InChI=1S/F6Si.2K/c1-7(2,3,4,5)6;;/q-2;2*+1;
(2)InChIKey=UUHPPUWEDCVPCO-UHFFFAOYSA-N;
(3)Smiles[Si-2](F)(F)(F)(F)(F)F.[K+].[K+];

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
frog LDLo subcutaneous 448mg/kg (448mg/kg)   Comptes Rendus des Seances de la Societe de Biologie et de Ses Filiales. Vol. 124, Pg. 133, 1937.
guinea pig LD50 oral 500mg/kg (500mg/kg)   "Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969Vol. 4, Pg. 327, 1969.
guinea pig LDLo subcutaneous 500mg/kg (500mg/kg)   Comptes Rendus des Seances de la Societe de Biologie et de Ses Filiales. Vol. 124, Pg. 133, 1937.
mouse LD50 oral 70mg/kg (70mg/kg) PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE)

BEHAVIORAL: ATAXIA

BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY)
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 53(11), Pg. 80, 1988.
rat LD50 oral 156mg/kg (156mg/kg) BEHAVIORAL: ATAXIA

PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE)

BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY)
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 53(11), Pg. 80, 1988.

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