1-Methyl-o-carborane

Base Information Edit

Chemical Name:1-Methyl-o-carborane
CAS No.:16872-10-9
Molecular Formula:C3H14 B10
Molecular Weight:158.254
Hs Code.:
Mol file:16872-10-9.mol

Synonyms:1-Methyl-1,2-dicarba-closo-dodecaborane;1-Methyl-1,2-dicarba-closo-dodecaborane(12);1-Methyl-1,2-dicarbadodecaborane(12);1-Methyl-closo-1,2-dicarbadodecaborane(12); 1-Methyl-o-carborane;1-Methyl-o-carborane(12); NSC 98962

Suppliers and Price of 1-Methyl-o-carborane

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Usbiological
1-Methyl-o-carborane
100mg
$ 460.00

American Custom Chemicals Corporation
1-METHYL-O-CARBORANE 95.00%
5MG
$ 503.05

Total 20 raw suppliers

Chemical Property of 1-Methyl-o-carborane Edit

Chemical Property:

Melting Point:216-218 °C
PSA：0.00000
LogP:-5.68630

Purity/Quality:

98% ^*data from raw suppliers

1-Methyl-o-carborane ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Use Description 1-Methyl-o-carborane is a chemical compound with applications in various fields. In the field of materials science and nuclear technology, it serves as a neutron absorber and radiation shielding material due to its ability to efficiently capture neutrons, making it valuable in the construction of radiation shielding materials for nuclear reactors and radiation therapy facilities. Its role is pivotal in ensuring the safety of personnel and preventing unwanted radiation exposure. Additionally, in organic chemistry, 1-Methyl-o-carborane can be employed as a building block for the creation of specialized organic compounds and ligands, contributing to the development of novel materials and catalysts with diverse applications. Its significance varies within these fields, but it consistently plays a critical role in advancing radiation protection and materials innovation across diverse scientific and industrial applications.

Technology Process of 1-Methyl-o-carborane

There total 53 articles about 1-Methyl-o-carborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 14078-85-4
1-methyl-2-carboxy-1,2-dicarba-closo-dodecaborane⁽¹²⁾

: C₄H₁₃B₁₀O₂^(1-)*K⁽¹⁺⁾

: 16872-10-9
1-methyl-o-carborane

Guidance literature:: 1-methyl-2-carboxy-1,2-dicarba-closo-dodecaborane⁽¹²⁾; With potassium hydride; In 1,2-dichloro-ethane; at 20 ℃; for 8h;

C₄H₁₃B₁₀O₂^(1-)*K⁽¹⁺⁾; With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; oxygen; potassium carbonate; In toluene; at 95 ℃; for 36h;
DOI:10.1002/anie.201605880

Reference yield: 85.0%

: 109-72-8,29786-93-4
n-butyllithium

: 392250-95-2
3-iodo-1-methyl-1,2-dicarba-closo-dodecaborane

: 16872-10-9
1-methyl-o-carborane

Guidance literature:: With (n-Bu)CCTMS; bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; (N2); using Schlenk techniques; addn. of 1 equiv. of n-BuLi to toluene soln. of 3-iodo-1-methyl-o-carborane, stirring at room temp. for 0.5 h, addn. of Pd(PPh3)4 (5 mol%), Ni(cod)2 (5 mol%) and (n-Bu)CC(TMS) (4 equiv.), heating at 110°C overnight; quenching with H2O, extn. with ether, removal of organic solvents, chromy. on silica gel using hexane as eluent; elem. anal.;
DOI:10.1021/ja1058789

Reference yield: 82.0%

: 17157-02-7
9-iodo-m-carborane

: 19496-84-5
1-bromomethyl-1,2-dicarba-closo-dodecaborane⁽¹²⁾

: 7439-95-4
magnesium

: 16872-10-9
1-methyl-o-carborane

: 9-(o-carboran-1-ylmethyl)-m-carborane

Guidance literature:: With methanol; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In diethyl ether; N2 atmosphere; heating (40-45°C, stirring, 40 h), decompn. with MeOH (0°C); washing (aq. HCl, water), drying (over CaCl2), chromy. (petroleum mether, benzene/petroleum ether 1:1), sublimation (120-170°C, 1 mm), recrystn.; elem. anal.;