2-Methyl-4'-(methylthio)-2-morpholinopropiophenone

Base Information Edit

Chemical Name:2-Methyl-4'-(methylthio)-2-morpholinopropiophenone
CAS No.:71868-10-5
Deprecated CAS:123584-61-2,125732-34-5,188793-69-3,133976-34-8,1254780-69-2,934687-53-3,1357159-95-5,1467104-11-5,2253103-99-8,1254780-69-2,125732-34-5,133976-34-8,1357159-95-5,188793-69-3,934687-53-3
Molecular Formula:C15H21NO2S
Molecular Weight:279.403
Hs Code.:29349990
European Community (EC) Number:400-600-6,615-621-8
UNII:722CLJ6H6K
DSSTox Substance ID:DTXSID8038857
Nikkaji Number:J73.113G
Wikidata:Q27266008
ChEMBL ID:CHEMBL1411716
Mol file:71868-10-5.mol

Synonyms:2-methyl-4'-(methylthio)-2-morpholinopropiophenone;MTMP cpd;MTMPP

Suppliers and Price of 2-Methyl-4'-(methylthio)-2-morpholinopropiophenone

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TCI Chemical
2-Methyl-4'-(methylthio)-2-morpholinopropiophenone >98.0%(GC)(T)
500g
$ 303.00

TCI Chemical
2-Methyl-4'-(methylthio)-2-morpholinopropiophenone >98.0%(GC)(T)
25g
$ 40.00

Sigma-Aldrich
2-Methyl-4′-(methylthio)-2-morpholinopropiophenone 98%
50g
$ 85.70

Matrix Scientific
2-Methyl-1-(4-(methylthio)phenyl)-2-morpholinopropan-1-one 95+%
10g
$ 12.00

Matrix Scientific
2-Methyl-1-(4-(methylthio)phenyl)-2-morpholinopropan-1-one 95+%
5g
$ 10.00

Matrix Scientific
2-Methyl-1-(4-(methylthio)phenyl)-2-morpholinopropan-1-one 95+%
25g
$ 19.00

Frontier Specialty Chemicals
2-Methyl-4'-(methylthio)-2-morpholinopropiophenone 99%
25g
$ 47.00

Frontier Specialty Chemicals
2-Methyl-4'-(methylthio)-2-morpholinopropiophenone 99%
5g
$ 13.00

Crysdot
2-Methyl-1-(4-(methylthio)phenyl)-2-morpholinopropan-1-one 95+%
500g
$ 114.00

Chemenu
2-Methyl-1-(4-(methylthio)phenyl)-2-morpholinopropan-1-one 95%
500g
$ 194.00

Total 129 raw suppliers

Chemical Property of 2-Methyl-4'-(methylthio)-2-morpholinopropiophenone Edit

Chemical Property:

Appearance/Colour:White to yellow powder
Vapor Pressure:0Pa at 25℃
Melting Point:74-76 °C
Boiling Point:420.1 °C at 760 mmHg
PKA:4.77±0.10(Predicted)
Flash Point:207.9 °C
PSA：54.84000
Density:1.15 g/cm³
LogP:2.63990
Storage Temp.:Keep in dark place,Sealed in dry,Room Temperature
Solubility.:162 in mg/100g standard fat at 20 ℃
Water Solubility.:17.9mg/L at 20℃
XLogP3:2.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:279.12930009
Heavy Atom Count:19
Complexity:305

Purity/Quality:

99% ^*data from raw suppliers

2-Methyl-4'-(methylthio)-2-morpholinopropiophenone >98.0%(GC)(T) ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xn,N
Hazard Codes:Xn,N
Statements: 22-51/53
Safety Statements: 22-61

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C(=O)C1=CC=C(C=C1)SC)N2CCOCC2

Technology Process of 2-Methyl-4'-(methylthio)-2-morpholinopropiophenone

There total 9 articles about 2-Methyl-4'-(methylthio)-2-morpholinopropiophenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.2%

: 110-91-8,99108-56-2
morpholine

: 2-methoxy-3,3-dimethyl-2-(4-methylthiophenyl)oxirane

: 71868-10-5
2-methyl-1-[4-(methylthio)phenyl]-2-morpholinopropan-1-one

Guidance literature:: With calcium hydroxide; at 20 - 138 ℃; for 20h;

Reference yield: 74.0%

: 1879-16-9
1-methoxy-4-methylsulfanyl-benzene

: 4-(2-methyl-2-morpholinopropanoyl)benzonitrile

: 71868-10-5
2-methyl-1-[4-(methylthio)phenyl]-2-morpholinopropan-1-one

Guidance literature:: With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; 1,2-bis-(dicyclohexylphosphino)ethane; In o-xylene; at 140 ℃; for 24h; Glovebox; Inert atmosphere;
DOI:10.1021/jacs.1c00529

Reference yield: 61.0%

: 110-91-8,99108-56-2
morpholine

: 53207-58-2
2-methyl-1-(4-(methylthio)phenyl)-propan-1-one

: 71868-10-5
2-methyl-1-[4-(methylthio)phenyl]-2-morpholinopropan-1-one

Guidance literature:: 2-methyl-1-(4-(methylthio)phenyl)-propan-1-one; With hexachloroethane; sodium methylate; In methanol; at 40 ℃; for 24h;

morpholine; With tetra(n-butyl)ammonium hydrogensulfate; sodium hydroxide; for 10h; Reagent/catalyst; Temperature; Reflux;